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- W3183060641 abstract "Single-atom catalysts (SACs) have recently been exploited for luminol-dissolved oxygen electrochemiluminescence (ECL); however, they still suffer from low sensitivity and narrow detection range for a real sample assay. In this work, we boost markedly the ECL response of the iron SAC (Fe-SAC)-based system, for the first time, by the excitation of two-dimensional plasmons derived from the Au@SiO2 nanomembrane. The plausible mechanism of plasmon enhancement in the Fe-SAC ECL system has been discussed. The constructed Fe-SAC ECL system has been applied for the ECL detection of dopamine, hemin, and mercury (Hg2+), with pretty low limits of detection of 0.1, 0.7, and 0.13 nM and wider linear ranges of 0.001–1.0, 0.001–10, and 0.01–0.5 nM, respectively, under optimal conditions." @default.
- W3183060641 created "2021-07-19" @default.
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- W3183060641 date "2021-07-05" @default.
- W3183060641 modified "2023-10-14" @default.
- W3183060641 title "Two-Dimensional-Plasmon-Boosted Iron Single-Atom Electrochemiluminescence for the Ultrasensitive Detection of Dopamine, Hemin, and Mercury" @default.
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- W3183060641 doi "https://doi.org/10.1021/acs.analchem.1c02232" @default.
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