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- W3183830334 endingPage "11956" @default.
- W3183830334 startingPage "11948" @default.
- W3183830334 abstract "We report a new class of four dimeric Co(II) complexes [Co2(bbpen)(X)2] (H2bbpen = N,N′-bis(2-hydroxybenzyl)-N,N′-bis(2-methylpyridyl)ethylenediamine) [X– = SCN (1), Cl (2), Br (3), and I (4)] with different coordination geometry of two Co(II) centers (trigonal-prismatic and pseudo-tetrahedral) and their magnetic study. Interestingly, the two Co(II) centers show two different types of magnetic anisotropy. State of the art ab initio CASSCF analysis reveals that the six-coordinate or the trigonal-prismatic Co(II) center possesses a consistently large negative axial zero-field splitting (negative D) parameter (∼−60 cm–1), while the four-coordinate or the pseudo-tetrahedral Co(II) center exhibits a range of D values from +13 to −23 cm–1. Ab initio calculations employing the lines model were used to estimate the magnetic exchange as both the Co(II) centers possess significant magnetic anisotropy. All the complexes display rare ferromagnetic interaction, and the strength of this interaction decreases as the ligand field on the pseudo-tetrahedral Co(II) center decreases from SCN– > Cl– > Br– > I–." @default.
- W3183830334 created "2021-08-02" @default.
- W3183830334 creator A5027699292 @default.
- W3183830334 creator A5030031955 @default.
- W3183830334 creator A5040324814 @default.
- W3183830334 creator A5054818199 @default.
- W3183830334 creator A5061111338 @default.
- W3183830334 date "2021-07-27" @default.
- W3183830334 modified "2023-10-17" @default.
- W3183830334 title "Modulation of Magnetic Anisotropy and Exchange Interaction in Phenoxide-Bridged Dinuclear Co(II) Complexes" @default.
- W3183830334 cites W1819117861 @default.
- W3183830334 cites W1969360633 @default.
- W3183830334 cites W1970474039 @default.
- W3183830334 cites W1973419089 @default.
- W3183830334 cites W1973955824 @default.
- W3183830334 cites W1976106561 @default.
- W3183830334 cites W1978708968 @default.
- W3183830334 cites W1979303409 @default.
- W3183830334 cites W1981084412 @default.
- W3183830334 cites W1981783914 @default.
- W3183830334 cites W1981810963 @default.
- W3183830334 cites W2001281409 @default.
- W3183830334 cites W2001740407 @default.
- W3183830334 cites W2018227294 @default.
- W3183830334 cites W2019693375 @default.
- W3183830334 cites W2019877780 @default.
- W3183830334 cites W2036420629 @default.
- W3183830334 cites W2037271600 @default.
- W3183830334 cites W2038028716 @default.
- W3183830334 cites W2040593414 @default.
- W3183830334 cites W2046080123 @default.
- W3183830334 cites W2046449218 @default.
- W3183830334 cites W2047000596 @default.
- W3183830334 cites W2048639761 @default.
- W3183830334 cites W2055685132 @default.
- W3183830334 cites W2059205366 @default.
- W3183830334 cites W2064621702 @default.
- W3183830334 cites W2070248735 @default.
- W3183830334 cites W2071167823 @default.
- W3183830334 cites W2080558656 @default.
- W3183830334 cites W2082104950 @default.
- W3183830334 cites W2085293698 @default.
- W3183830334 cites W2088672247 @default.
- W3183830334 cites W2097764239 @default.
- W3183830334 cites W2098702989 @default.
- W3183830334 cites W2098899618 @default.
- W3183830334 cites W2109603371 @default.
- W3183830334 cites W2115794714 @default.
- W3183830334 cites W2117867509 @default.
- W3183830334 cites W2122205971 @default.
- W3183830334 cites W2126781151 @default.
- W3183830334 cites W2135004772 @default.
- W3183830334 cites W2140404346 @default.
- W3183830334 cites W2142199780 @default.
- W3183830334 cites W2152464446 @default.
- W3183830334 cites W2168909782 @default.
- W3183830334 cites W2175930880 @default.
- W3183830334 cites W2194352041 @default.
- W3183830334 cites W2278356249 @default.
- W3183830334 cites W2284894100 @default.
- W3183830334 cites W2312573082 @default.
- W3183830334 cites W2321893305 @default.
- W3183830334 cites W2328253128 @default.
- W3183830334 cites W2332200090 @default.
- W3183830334 cites W2335210990 @default.
- W3183830334 cites W2347124381 @default.
- W3183830334 cites W2414402924 @default.
- W3183830334 cites W2439570865 @default.
- W3183830334 cites W2466015345 @default.
- W3183830334 cites W2472971450 @default.
- W3183830334 cites W2474440651 @default.
- W3183830334 cites W2523874369 @default.
- W3183830334 cites W2530854555 @default.
- W3183830334 cites W2538683140 @default.
- W3183830334 cites W2560057392 @default.
- W3183830334 cites W2590766540 @default.
- W3183830334 cites W2596876884 @default.
- W3183830334 cites W2605109432 @default.
- W3183830334 cites W2606073954 @default.
- W3183830334 cites W2616557405 @default.
- W3183830334 cites W2618143612 @default.
- W3183830334 cites W2739439285 @default.
- W3183830334 cites W2771656513 @default.
- W3183830334 cites W2785687508 @default.
- W3183830334 cites W2890862781 @default.
- W3183830334 cites W2894557875 @default.
- W3183830334 cites W2904329093 @default.
- W3183830334 cites W2921661131 @default.
- W3183830334 cites W2964693012 @default.
- W3183830334 cites W2971968767 @default.
- W3183830334 cites W3006904171 @default.
- W3183830334 cites W3045612742 @default.
- W3183830334 cites W3124921712 @default.
- W3183830334 cites W4232406903 @default.
- W3183830334 cites W4235755370 @default.
- W3183830334 cites W4240970816 @default.
- W3183830334 doi "https://doi.org/10.1021/acs.inorgchem.1c00956" @default.
- W3183830334 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34314144" @default.