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- W3184677924 abstract "Abstract A palladium‐catalyzed (Pd(PPh 3 ) 4 /Ag 2 O/PivOH) C 2 ‐regioselective direct dehydrogenative alkynylation of unsubstituted selenophene was achieved. The selenophenes substituted with R 1 groups at 2‐position can be C 5 ‐alkynylated with a variety of 4‐substituted phenylacetylenes (R 2 groups). The R 1 and R 2 can be either electron‐withdrawing or electron‐donating groups, demonstrating a wide range of substrate scope with various functional group tolerance. The mono/C 2 ‐alkynylated selenophenes can subsequently undergo the second direct alkynylation at C 5 ‐position to afford symmetrical or unsymmetrical donor‐π‐acceptor 2,5‐dialkynylated selenophenes. magnified image" @default.
- W3184677924 created "2021-08-02" @default.
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- W3184677924 date "2021-08-19" @default.
- W3184677924 modified "2023-10-11" @default.
- W3184677924 title "Palladium‐Catalyzed Direct Cross‐Dehydrogenative Alkynylation of Selenophenes" @default.
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- W3184677924 doi "https://doi.org/10.1002/adsc.202100741" @default.
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