Matches in SemOpenAlex for { <https://semopenalex.org/work/W3185079374> ?p ?o ?g. }
- W3185079374 endingPage "12899" @default.
- W3185079374 startingPage "12890" @default.
- W3185079374 abstract "Abstract Chemical fixation of CO 2 as C1 source at ambient temperature and low pressure is an energy‐saving way to make use of the green‐house gas, but it still remains a challenge since efficient catalyst with high catalytic active sites is required. Here, a novel monoclinic azo‐functionalized Zr‐based metal−organic polyhedron (Zr‐AZDA) has been prepared and applied in CO 2 fixation with epoxides. The inherent azo groups not only endow Zr‐AZDA with good solubilization, but also act as basic sites to enrich CO 2 showing efficient synergistic catalysis as confirmed by TPD‐CO 2 analysis. XPS results demonstrate that the Zr active sites in Zr‐AZDA possess suitable Lewis acidity, which satisfies both substrates activation and products desorption. DFT calculation indicates the energy barrier of the rate‐determining step in CO 2 cycloaddition could be reduced remarkably (by ca. 60.9 %) in the presence of Zr‐AZDA, which may rationalize the mild and efficient reaction condition employed (80 °C and 1 atm of CO 2 ). The work provides an effective multi‐functional cooperative method for improvement of CO 2 cycloaddition." @default.
- W3185079374 created "2021-08-02" @default.
- W3185079374 creator A5002448054 @default.
- W3185079374 creator A5012698401 @default.
- W3185079374 creator A5017964156 @default.
- W3185079374 creator A5056147381 @default.
- W3185079374 creator A5058219078 @default.
- W3185079374 creator A5088777194 @default.
- W3185079374 date "2021-08-05" @default.
- W3185079374 modified "2023-10-15" @default.
- W3185079374 title "Azo‐Functionalized Zirconium‐Based Metal−Organic Polyhedron as an Efficient Catalyst for CO <sub>2</sub> Fixation with Epoxides" @default.
- W3185079374 cites W1201284500 @default.
- W3185079374 cites W1973187203 @default.
- W3185079374 cites W1980240246 @default.
- W3185079374 cites W1990727323 @default.
- W3185079374 cites W1992576234 @default.
- W3185079374 cites W1992956895 @default.
- W3185079374 cites W1994511147 @default.
- W3185079374 cites W2003192950 @default.
- W3185079374 cites W2004265232 @default.
- W3185079374 cites W2004550299 @default.
- W3185079374 cites W2005614848 @default.
- W3185079374 cites W2007108202 @default.
- W3185079374 cites W2008643556 @default.
- W3185079374 cites W2024459961 @default.
- W3185079374 cites W2029525813 @default.
- W3185079374 cites W2034530793 @default.
- W3185079374 cites W2045277089 @default.
- W3185079374 cites W2065941271 @default.
- W3185079374 cites W2081733273 @default.
- W3185079374 cites W2084406030 @default.
- W3185079374 cites W2085981529 @default.
- W3185079374 cites W2094473965 @default.
- W3185079374 cites W2104613429 @default.
- W3185079374 cites W2118257359 @default.
- W3185079374 cites W2121246631 @default.
- W3185079374 cites W2126447293 @default.
- W3185079374 cites W2129977671 @default.
- W3185079374 cites W2149749098 @default.
- W3185079374 cites W2156208893 @default.
- W3185079374 cites W2156824383 @default.
- W3185079374 cites W2162561859 @default.
- W3185079374 cites W2168708380 @default.
- W3185079374 cites W2168838340 @default.
- W3185079374 cites W2283564633 @default.
- W3185079374 cites W2298138776 @default.
- W3185079374 cites W2301164866 @default.
- W3185079374 cites W2319442421 @default.
- W3185079374 cites W2320190116 @default.
- W3185079374 cites W2332966884 @default.
- W3185079374 cites W2345700910 @default.
- W3185079374 cites W2541329406 @default.
- W3185079374 cites W2557004950 @default.
- W3185079374 cites W2564544588 @default.
- W3185079374 cites W2565669272 @default.
- W3185079374 cites W2605737825 @default.
- W3185079374 cites W2605849292 @default.
- W3185079374 cites W2616390082 @default.
- W3185079374 cites W2618127528 @default.
- W3185079374 cites W2766326759 @default.
- W3185079374 cites W2766920508 @default.
- W3185079374 cites W2773402629 @default.
- W3185079374 cites W2791753012 @default.
- W3185079374 cites W2793243047 @default.
- W3185079374 cites W2802086534 @default.
- W3185079374 cites W2805671282 @default.
- W3185079374 cites W2807929390 @default.
- W3185079374 cites W2887096073 @default.
- W3185079374 cites W2890479580 @default.
- W3185079374 cites W2892954861 @default.
- W3185079374 cites W2898217929 @default.
- W3185079374 cites W2906576074 @default.
- W3185079374 cites W2924984000 @default.
- W3185079374 cites W2945191275 @default.
- W3185079374 cites W2969162933 @default.
- W3185079374 cites W2973654550 @default.
- W3185079374 cites W2998635116 @default.
- W3185079374 cites W2998869755 @default.
- W3185079374 cites W3019642045 @default.
- W3185079374 cites W3023196927 @default.
- W3185079374 cites W3032119421 @default.
- W3185079374 cites W3033122827 @default.
- W3185079374 cites W3033672738 @default.
- W3185079374 cites W3083397129 @default.
- W3185079374 cites W3098146424 @default.
- W3185079374 cites W3127049286 @default.
- W3185079374 cites W3137152869 @default.
- W3185079374 cites W3139985601 @default.
- W3185079374 doi "https://doi.org/10.1002/chem.202102089" @default.
- W3185079374 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34288181" @default.
- W3185079374 hasPublicationYear "2021" @default.
- W3185079374 type Work @default.
- W3185079374 sameAs 3185079374 @default.
- W3185079374 citedByCount "6" @default.
- W3185079374 countsByYear W31850793742022 @default.
- W3185079374 countsByYear W31850793742023 @default.
- W3185079374 crossrefType "journal-article" @default.
- W3185079374 hasAuthorship W3185079374A5002448054 @default.