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• W3185174688 endingPage "12135" @default.
• W3185174688 startingPage "12129" @default.
• W3185174688 abstract "To date, numerous zirconium cluster-based metal–organic frameworks (Zr-MOFs) with attractive physical properties have been achieved thanks to tailorable organic linkers and versatile Zr clusters. Nevertheless, in comparison with the most-used high-symmetry organic linkers, low-symmetry linkers have rarely been exploited in the construction of Zr-MOFs. Despite challenges in predicting the structure and topology of the MOF, linker desymmetrization presents opportunities for the design of Zr-MOFs with unusual topologies and unexpected functionalities. Herein, we report for the first time the construction of two robust Zr-MOFs (IAM-7 and IAM-8) from two pyrrolo-pyrrole-based low-symmetry tetracarboxylate linkers with a rare rhombic shape. The low symmetry of the linkers arises from the asymmetric pyrrolo-pyrrole core and the varying branch lengths, which play a critical role in the structural diversity between IAM-7 and IAM-8 seen from the structural analysis and lead to hydrophilic channels that contain uncoordinated carboxylate groups in the structure of IAM-7. Furthermore, the proton conductivity of IAM-7 displays a high temperature and humidity dependence where the proton conductivity increases from 2.84 × 10–8 S cm–1 at 30 °C and 40% relative humidity (RH) to 1.42 × 10–2 S cm–1 at 90 °C and 95% RH, making it among one of the most conductive Zr-MOFs. This work not only enriches the library of Zr-MOFs but also offers a platform for the design of low-symmetry linkers toward the structural diversity or irregularity of MOFs as well as their structure-related properties." @default.
• W3185174688 created "2021-08-02" @default.
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• W3185174688 date "2021-07-26" @default.
• W3185174688 modified "2023-10-15" @default.
• W3185174688 title "Construction of Highly Proton-Conductive Zr(IV)-Based Metal–Organic Frameworks From Pyrrolo-pyrrole-Based Linkers with a Rhombic Shape" @default.
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• W3185174688 doi "https://doi.org/10.1021/acs.inorgchem.1c01336" @default.
• W3185174688 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34310114" @default.
• W3185174688 hasPublicationYear "2021" @default.
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