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- W3185602432 endingPage "109693" @default.
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- W3185602432 abstract "The existing form of copper and its release mechanism from the passive film of Ti-7Cu alloy was studied by Quantitative analysis of depth profile and series of electrochemical tests. Results were interpreted within the Point Defect Model-II. Copper does not form any p-type (cuprous or cupric) oxide but preferentially oxidises at the metal/film interface and segregated as Cu interstitials Cui+ and become substituted as CuTix' in the oxygen-deficient TiO2-x barrier layer having n-type semiconducting character. Eventually, the segregated species of Cu preferentially dissolute through the film as Cu ions into the solution at film/solution interface via the Esaki-tunnelling effect." @default.
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- W3185602432 date "2021-09-01" @default.
- W3185602432 modified "2023-10-17" @default.
- W3185602432 title "Study the existing form of copper (p-type oxide/segregation) and its release mechanism from the passive film of Ti-7Cu alloy" @default.
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- W3185602432 doi "https://doi.org/10.1016/j.corsci.2021.109693" @default.
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