FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3185851558> ?p ?o ?g. }

• W3185851558 endingPage "111303" @default.
• W3185851558 startingPage "111303" @default.
• W3185851558 abstract "There is a growing interest in the sustainable synthesis of Metal-Organic Framework materials (MOFs). This work addresses the exceptional ability of Ce(IV) for the preparation of high-quality MOFs based on carboxylates at room temperature, in water as solvent, and without any energy input. Thus, crystalline terephthalate-based UiO-66(Ce), fumarate-based UiO-66(Ce) and Ce-MOF-808 were successfully synthesized at room temperature by various new approaches. All these methodologies are novel, rapid, simple, reproducible, inexpensive, energetically efficient and relatively environmentally benign compared with the usual conventional methodologies and, unlike other room-temperature synthesis, leads to highly-crystalline samples. In particular, (i) both terephthalate- and fumarate-based UiO-66(Ce) were synthesized using water as a sole solvent and in the absence of any modulator or any other additive; (ii) terephthalate-based UiO-66(Ce) was prepared under systematically-designed different water/DMF molar ratio, selecting these solvents in order to start from clear solutions of both metal and linker sources, respectively; and (iii) terephthalate-based UiO-66(Ce) and Ce-MOF-808 were prepared in the presence of either acetic acid or formic acid as modulators, respectively. Therefore, this work provides novel strategies for the preparation of tetravalent metal based MOFs, which are in general scarce with respect to the whole number of known MOFs, particularly at room temperature." @default.
• W3185851558 created "2021-08-02" @default.
• W3185851558 creator A5029024180 @default.
• W3185851558 creator A5059490996 @default.
• W3185851558 creator A5079749026 @default.
• W3185851558 date "2021-09-01" @default.
• W3185851558 modified "2023-10-15" @default.
• W3185851558 title "Room temperature synthesis of high-quality Ce(IV)-based MOFs in water" @default.
• W3185851558 cites W1758136057 @default.
• W3185851558 cites W1977523466 @default.
• W3185851558 cites W1978861535 @default.
• W3185851558 cites W1981641893 @default.
• W3185851558 cites W1982362492 @default.
• W3185851558 cites W1986238480 @default.
• W3185851558 cites W1990918587 @default.
• W3185851558 cites W1992907854 @default.
• W3185851558 cites W2007661885 @default.
• W3185851558 cites W2009563160 @default.
• W3185851558 cites W2042509191 @default.
• W3185851558 cites W2048030541 @default.
• W3185851558 cites W2058459839 @default.
• W3185851558 cites W2101391523 @default.
• W3185851558 cites W2112273770 @default.
• W3185851558 cites W2115427755 @default.
• W3185851558 cites W2141939342 @default.
• W3185851558 cites W2283564633 @default.
• W3185851558 cites W2317566433 @default.
• W3185851558 cites W2333547949 @default.
• W3185851558 cites W2343126244 @default.
• W3185851558 cites W2419604106 @default.
• W3185851558 cites W2518995369 @default.
• W3185851558 cites W2553155156 @default.
• W3185851558 cites W2569973408 @default.
• W3185851558 cites W2591737146 @default.
• W3185851558 cites W2594164608 @default.
• W3185851558 cites W2614976445 @default.
• W3185851558 cites W2618624048 @default.
• W3185851558 cites W2621605813 @default.
• W3185851558 cites W2771270850 @default.
• W3185851558 cites W2890480171 @default.
• W3185851558 cites W2896698344 @default.
• W3185851558 cites W2901282570 @default.
• W3185851558 cites W2912483554 @default.
• W3185851558 cites W2940579169 @default.
• W3185851558 cites W2969111834 @default.
• W3185851558 cites W2970315737 @default.
• W3185851558 cites W2980129157 @default.
• W3185851558 cites W2987989434 @default.
• W3185851558 cites W2995923076 @default.
• W3185851558 cites W3014055873 @default.
• W3185851558 cites W3014398003 @default.
• W3185851558 cites W3028184535 @default.
• W3185851558 cites W3036061884 @default.
• W3185851558 cites W3036902998 @default.
• W3185851558 cites W3093482012 @default.
• W3185851558 cites W3101452720 @default.
• W3185851558 cites W3103915194 @default.
• W3185851558 cites W3110306154 @default.
• W3185851558 cites W4250661274 @default.
• W3185851558 doi "https://doi.org/10.1016/j.micromeso.2021.111303" @default.
• W3185851558 hasPublicationYear "2021" @default.
• W3185851558 type Work @default.
• W3185851558 sameAs 3185851558 @default.
• W3185851558 citedByCount "19" @default.
• W3185851558 countsByYear W31858515582021 @default.
• W3185851558 countsByYear W31858515582022 @default.
• W3185851558 countsByYear W31858515582023 @default.
• W3185851558 crossrefType "journal-article" @default.
• W3185851558 hasAuthorship W3185851558A5029024180 @default.
• W3185851558 hasAuthorship W3185851558A5059490996 @default.
• W3185851558 hasAuthorship W3185851558A5079749026 @default.
• W3185851558 hasBestOaLocation W31858515581 @default.
• W3185851558 hasConcept C111919701 @default.
• W3185851558 hasConcept C127413603 @default.
• W3185851558 hasConcept C150394285 @default.
• W3185851558 hasConcept C178790620 @default.
• W3185851558 hasConcept C179104552 @default.
• W3185851558 hasConcept C179366358 @default.
• W3185851558 hasConcept C185592680 @default.
• W3185851558 hasConcept C191897082 @default.
• W3185851558 hasConcept C192562407 @default.
• W3185851558 hasConcept C2776011623 @default.
• W3185851558 hasConcept C2776673659 @default.
• W3185851558 hasConcept C2777379063 @default.
• W3185851558 hasConcept C2780471494 @default.
• W3185851558 hasConcept C2780557392 @default.
• W3185851558 hasConcept C41008148 @default.
• W3185851558 hasConcept C42360764 @default.
• W3185851558 hasConcept C544153396 @default.
• W3185851558 hasConceptScore W3185851558C111919701 @default.
• W3185851558 hasConceptScore W3185851558C127413603 @default.
• W3185851558 hasConceptScore W3185851558C150394285 @default.
• W3185851558 hasConceptScore W3185851558C178790620 @default.
• W3185851558 hasConceptScore W3185851558C179104552 @default.
• W3185851558 hasConceptScore W3185851558C179366358 @default.
• W3185851558 hasConceptScore W3185851558C185592680 @default.
• W3185851558 hasConceptScore W3185851558C191897082 @default.
• W3185851558 hasConceptScore W3185851558C192562407 @default.

• next