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- W3186114189 endingPage "131584" @default.
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- W3186114189 abstract "Continual input of neonicotinoid insecticides occurs in the citrus orchards from southern China. However, it is still unknown about the variations in the distribution and accumulation of neonicotinoids in soil profiles along a long-term chronosequence of cultivation and the driving factors contributing to these shifts. Here, changes of neonicotinoids in the 0–100 cm soil profiles with distinct orchard cultivation age (1, 10, and 20 years) were investigated, and their related factors were further determined. The results showed that the total levels of five target neonicotinoids (∑5NEOs) in the soil profiles were in the range of 0–25.76 ng/g dw. Imidacloprid was the most dominating neonicotinoid, followed by thiamethoxam. We observed higher neonicotinoid accumulations in the soil profiles from the citrus orchards after 10 and 20 years of cultivation. Neonicotinoids migrated deeper into the soil profiles in orchards with a longer time since cultivation. Imidacloprid, thiamethoxam, and the total amount of neonicotinoid (∑5NEOs) were mainly affected by the cultivation age of citrus orchards (accounting for 58.9% variance; P < 0.001); whereas clothianidin, acetamiprid, and thiacloprid were mainly influenced by soil depths (accounting for 66.9–85.2% variance; P < 0.05). Redundancy analyzes further indicated that the enhanced accumulation of neonicotinoids was mainly correlated with the increase of soil organic carbon (SOC) content and soil porosity, and the reduction of bulk density in the profiles of citrus orchards with increasing cultivation age. This study highlights the finding that we should give more concerns about the contamination and ecological risks of neonicotinoids in the orchards with a long cultivation age." @default.
- W3186114189 created "2021-08-02" @default.
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- W3186114189 date "2022-01-01" @default.
- W3186114189 modified "2023-10-15" @default.
- W3186114189 title "Persistence and vertical distribution of neonicotinoids in soils under different citrus orchards chrono sequences from southern China" @default.
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- W3186114189 doi "https://doi.org/10.1016/j.chemosphere.2021.131584" @default.
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