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- W3186123852 abstract "New mononuclear complex [NiLβ-pic] has been synthesized by the reaction of Ni(II) acetate with salicylaldehyde 3-azacyclothiosemicarbazone (H2L) in the presence heterocyclic base, β-picoline as an auxiliary ligand. The complex has been investigated by elemental analysis, FT-IR, UV-Vis, 1H NMR and 13C NMR spectroscopy. These data show that the thiosemicarbazone acts as a dianionic tridentate ligand and coordinated to the metal through azomethine nitrogen, thioiminolate sulfur and phenolate oxygen. The coordination sphere is completed by β-picoline. The magnetic susceptibility measurement indicates that the complex is mononuclear and diamagnetic. The structure of the compound is also confirmed by single crystal X-ray crystallography and was found to be distorted square planar in geometry around Ni(II) metal ion centre in which the angles deviated from ideal 90° with a maximum value of 6.85° occupied by azomethine nitrogen, thiolato sulfur, phenolato oxygen and pyridyl nitrogen atoms. Hirshfeld surface analysis (dnorm surfaces and two-dimensional fingerprint plots) for the compound were performed and discussed." @default.
- W3186123852 created "2021-08-02" @default.
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- W3186123852 date "2021-10-01" @default.
- W3186123852 modified "2023-10-09" @default.
- W3186123852 title "Synthesis, crystallographic structure and hirshfeld surface analysis of nickel(II) chelate derived from O,N,S-donor tridentate thiosemicarbazone" @default.
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- W3186123852 doi "https://doi.org/10.1016/j.cdc.2021.100758" @default.
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