Matches in SemOpenAlex for { <https://semopenalex.org/work/W3186158251> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W3186158251 endingPage "5997" @default.
- W3186158251 startingPage "5993" @default.
- W3186158251 abstract "We report herein a nickel-catalyzed ring-opening allylation of cyclopropanols with allylic carbonates that occurs under mild and neutral conditions. The reaction displays linear selectivity for both linear and branched acyclic allylic carbonates and is also applicable to cyclic allylic carbonates, affording a variety of δ,e-unsaturated ketones in moderate to good yields. Mechanistic experiments are in accord with a catalytic cycle involving decarboxylative oxidative addition of allylic carbonate to Ni(0), alkoxide exchange with cyclopropanol, cyclopropoxide-to-homoenolate conversion on Ni(II), and C-C reductive elimination." @default.
- W3186158251 created "2021-08-02" @default.
- W3186158251 creator A5024512544 @default.
- W3186158251 creator A5026392182 @default.
- W3186158251 creator A5073041704 @default.
- W3186158251 date "2021-07-22" @default.
- W3186158251 modified "2023-09-26" @default.
- W3186158251 title "Nickel-Catalyzed Ring-Opening Allylation of Cyclopropanols via Homoenolate" @default.
- W3186158251 cites W1552045685 @default.
- W3186158251 cites W1971406006 @default.
- W3186158251 cites W2029791313 @default.
- W3186158251 cites W2034789162 @default.
- W3186158251 cites W2165583917 @default.
- W3186158251 cites W2326060735 @default.
- W3186158251 cites W2343752527 @default.
- W3186158251 cites W2783868504 @default.
- W3186158251 cites W2891807423 @default.
- W3186158251 cites W2922829941 @default.
- W3186158251 cites W2945915625 @default.
- W3186158251 cites W2950904817 @default.
- W3186158251 cites W2950975549 @default.
- W3186158251 cites W2980911000 @default.
- W3186158251 cites W3033937786 @default.
- W3186158251 cites W3089846392 @default.
- W3186158251 cites W3093912291 @default.
- W3186158251 cites W3096737109 @default.
- W3186158251 cites W3136846868 @default.
- W3186158251 cites W2101530173 @default.
- W3186158251 doi "https://doi.org/10.1021/acs.orglett.1c02072" @default.
- W3186158251 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34291932" @default.
- W3186158251 hasPublicationYear "2021" @default.
- W3186158251 type Work @default.
- W3186158251 sameAs 3186158251 @default.
- W3186158251 citedByCount "14" @default.
- W3186158251 countsByYear W31861582512021 @default.
- W3186158251 countsByYear W31861582512022 @default.
- W3186158251 countsByYear W31861582512023 @default.
- W3186158251 crossrefType "journal-article" @default.
- W3186158251 hasAuthorship W3186158251A5024512544 @default.
- W3186158251 hasAuthorship W3186158251A5026392182 @default.
- W3186158251 hasAuthorship W3186158251A5073041704 @default.
- W3186158251 hasConcept C155647269 @default.
- W3186158251 hasConcept C161790260 @default.
- W3186158251 hasConcept C178790620 @default.
- W3186158251 hasConcept C185592680 @default.
- W3186158251 hasConcept C21951064 @default.
- W3186158251 hasConcept C2780378348 @default.
- W3186158251 hasConcept C504270822 @default.
- W3186158251 hasConceptScore W3186158251C155647269 @default.
- W3186158251 hasConceptScore W3186158251C161790260 @default.
- W3186158251 hasConceptScore W3186158251C178790620 @default.
- W3186158251 hasConceptScore W3186158251C185592680 @default.
- W3186158251 hasConceptScore W3186158251C21951064 @default.
- W3186158251 hasConceptScore W3186158251C2780378348 @default.
- W3186158251 hasConceptScore W3186158251C504270822 @default.
- W3186158251 hasFunder F4320320751 @default.
- W3186158251 hasIssue "15" @default.
- W3186158251 hasLocation W31861582511 @default.
- W3186158251 hasOpenAccess W3186158251 @default.
- W3186158251 hasPrimaryLocation W31861582511 @default.
- W3186158251 hasRelatedWork W1994291208 @default.
- W3186158251 hasRelatedWork W2000462598 @default.
- W3186158251 hasRelatedWork W2012852568 @default.
- W3186158251 hasRelatedWork W2036221307 @default.
- W3186158251 hasRelatedWork W2081070655 @default.
- W3186158251 hasRelatedWork W2087419310 @default.
- W3186158251 hasRelatedWork W2159801338 @default.
- W3186158251 hasRelatedWork W2388796462 @default.
- W3186158251 hasRelatedWork W2566714014 @default.
- W3186158251 hasRelatedWork W3015795223 @default.
- W3186158251 hasVolume "23" @default.
- W3186158251 isParatext "false" @default.
- W3186158251 isRetracted "false" @default.
- W3186158251 magId "3186158251" @default.
- W3186158251 workType "article" @default.