FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3186177435> ?p ?o ?g. }

• W3186177435 endingPage "167" @default.
• W3186177435 startingPage "156" @default.
• W3186177435 abstract "Environmental context The molecular organisation of humic substances is key to understanding various natural and engineered processes, such as metal speciation and bioavailability. Two main models have been proposed: polymeric organisation and supramolecular organisation. A physicochemical approach, based on the interaction of humic acid with increasing amounts of cationic surfactants, leads to a sequence of molecular structures that provides support to the supramolecular view of humic organisation. Abstract The structural organisation of extracted humic matter, polymeric or supramolecular, has been a long-standing controversial issue. In this paper, we show that the interaction between a reference humic material, the Suwannee River Humic Acid (SRHA), and a homologous series of cationic surfactants (n-alkyl trimethyl ammonium chloride) provides key insights to resolve the controversy. By combining measurements of turbidity, electrophoretic mobility, surface tension and cryogenic transmission electron microscopy, we show that: (i) the binding of cationic surfactant to the anionic humic acid is initially triggered by electrostatic interactions; (ii) the contrasting evolution of turbidity–surfactant concentration curves implies that the surfactant alkyl chain interacts with the hydrophobic moieties of humic matter from very low concentrations of surfactant; (iii) a drastic restructuring of humic matter occurs on surfactant binding, which brings out supplementary anionic humic sites; (iv) in the presence of C12 cationic surfactant, SRHA spontaneously forms stable nanoscale unilamellar vesicles, which, in addition to the high surface activity of complexes, could be of interest in the remediation of oil-contaminated environments; (v) the sequence of molecular structures obtained from SRHA with increasing amounts of C12-cationic surfactant – humic-rich vesicles, aggregates, surfactant-rich vesicles – bears striking similarities with the phase behaviour of aqueous mixtures of anionic and cationic surfactants, thus supporting the supramolecular view of humic structure." @default.
• W3186177435 created "2021-08-02" @default.
• W3186177435 creator A5012175936 @default.
• W3186177435 creator A5024072979 @default.
• W3186177435 creator A5037173402 @default.
• W3186177435 creator A5046752606 @default.
• W3186177435 creator A5048240445 @default.
• W3186177435 creator A5065596443 @default.
• W3186177435 creator A5070054996 @default.
• W3186177435 date "2021-07-19" @default.
• W3186177435 modified "2023-10-18" @default.
• W3186177435 title "Complexes of humic acid with cationic surfactants support the supramolecular view of extracted humic matter" @default.
• W3186177435 cites W170085732 @default.
• W3186177435 cites W1966581690 @default.
• W3186177435 cites W1969533963 @default.
• W3186177435 cites W1970037992 @default.
• W3186177435 cites W1971095312 @default.
• W3186177435 cites W1983845801 @default.
• W3186177435 cites W1986401941 @default.
• W3186177435 cites W1987156875 @default.
• W3186177435 cites W1988236596 @default.
• W3186177435 cites W1989071269 @default.
• W3186177435 cites W1991107910 @default.
• W3186177435 cites W1992978916 @default.
• W3186177435 cites W1993081561 @default.
• W3186177435 cites W1997449204 @default.
• W3186177435 cites W2000966264 @default.
• W3186177435 cites W2001147920 @default.
• W3186177435 cites W2006117571 @default.
• W3186177435 cites W2007217171 @default.
• W3186177435 cites W2009122150 @default.
• W3186177435 cites W2010391014 @default.
• W3186177435 cites W2011083420 @default.
• W3186177435 cites W2016784613 @default.
• W3186177435 cites W2018482731 @default.
• W3186177435 cites W2022512900 @default.
• W3186177435 cites W2027568599 @default.
• W3186177435 cites W2028860765 @default.
• W3186177435 cites W2031042771 @default.
• W3186177435 cites W2031876788 @default.
• W3186177435 cites W2036350063 @default.
• W3186177435 cites W2037999067 @default.
• W3186177435 cites W2043479819 @default.
• W3186177435 cites W2044998541 @default.
• W3186177435 cites W2048398422 @default.
• W3186177435 cites W2051406683 @default.
• W3186177435 cites W2061078366 @default.
• W3186177435 cites W2068202530 @default.
• W3186177435 cites W2068608770 @default.
• W3186177435 cites W2071349845 @default.
• W3186177435 cites W2074321916 @default.
• W3186177435 cites W2076041399 @default.
• W3186177435 cites W2080445279 @default.
• W3186177435 cites W2082287688 @default.
• W3186177435 cites W2083498133 @default.
• W3186177435 cites W2086626257 @default.
• W3186177435 cites W2089071157 @default.
• W3186177435 cites W2091208364 @default.
• W3186177435 cites W2093773917 @default.
• W3186177435 cites W2094939488 @default.
• W3186177435 cites W2111694278 @default.
• W3186177435 cites W2130299659 @default.
• W3186177435 cites W2141374683 @default.
• W3186177435 cites W2172154998 @default.
• W3186177435 cites W2200817828 @default.
• W3186177435 cites W2321548141 @default.
• W3186177435 cites W2330842388 @default.
• W3186177435 cites W2331605289 @default.
• W3186177435 cites W2357256969 @default.
• W3186177435 cites W2522453007 @default.
• W3186177435 cites W2738320867 @default.
• W3186177435 cites W2783220316 @default.
• W3186177435 cites W2803104938 @default.
• W3186177435 cites W2907983490 @default.
• W3186177435 cites W2922376493 @default.
• W3186177435 cites W2935307208 @default.
• W3186177435 cites W2946973691 @default.
• W3186177435 cites W2970668908 @default.
• W3186177435 cites W2972956439 @default.
• W3186177435 cites W4235280336 @default.
• W3186177435 cites W4245001669 @default.
• W3186177435 cites W4247982981 @default.
• W3186177435 doi "https://doi.org/10.1071/en21031" @default.
• W3186177435 hasPublicationYear "2021" @default.
• W3186177435 type Work @default.
• W3186177435 sameAs 3186177435 @default.
• W3186177435 citedByCount "2" @default.
• W3186177435 countsByYear W31861774352022 @default.
• W3186177435 countsByYear W31861774352023 @default.
• W3186177435 crossrefType "journal-article" @default.
• W3186177435 hasAuthorship W3186177435A5012175936 @default.
• W3186177435 hasAuthorship W3186177435A5024072979 @default.
• W3186177435 hasAuthorship W3186177435A5037173402 @default.
• W3186177435 hasAuthorship W3186177435A5046752606 @default.
• W3186177435 hasAuthorship W3186177435A5048240445 @default.
• W3186177435 hasAuthorship W3186177435A5065596443 @default.
• W3186177435 hasAuthorship W3186177435A5070054996 @default.
• W3186177435 hasBestOaLocation W31861774352 @default.

• next