Matches in SemOpenAlex for { <https://semopenalex.org/work/W3186751435> ?p ?o ?g. }
- W3186751435 endingPage "8698" @default.
- W3186751435 startingPage "8682" @default.
- W3186751435 abstract "Reduction of nitric oxide (NO) to nitrous oxide (N2O) is associated with immense biological and health implications. Flavodiiron nitric oxide reductases (FNORs) are diiron containing enzymes that catalyze the two electron reduction of NO to N2O and help certain pathogenic bacteria to survive under nitrosative stress in anaerobic growth conditions. Consequently, invading bacteria can proliferate inside the body of mammals by bypassing the immune defense mechanism involving NO and may thus lead to harmful infections. Various mechanisms, namely the direct reduction, semireduction, superreduction and hyponitrite mechanisms, have been proposed over time for catalytic NO reduction by FNORs. Model studies in relation to the diiron active site of FNORs have immensely helped to replicate the minimal structure-reactivity relationship and to understand the mechanism of NO reduction. A brief overview of the FNOR activity and the proposed reaction mechanisms followed by a systematic description and detailed analysis of the model studies is presented, which describes the development in the area of NO reduction by diiron complexes and its implications. A great deal of successful modeling chemistry as well as the shortcomings related to the synthesis and reactivity studies is discussed in detail. Finally, future prospects in this particular area of research are proposed, which in due course may bring more clarity in the understanding of this important redox reaction." @default.
- W3186751435 created "2021-08-02" @default.
- W3186751435 creator A5038509972 @default.
- W3186751435 creator A5068242856 @default.
- W3186751435 creator A5087760384 @default.
- W3186751435 date "2021-01-01" @default.
- W3186751435 modified "2023-10-17" @default.
- W3186751435 title "Reduction of NO by diiron complexes in relation to flavodiiron nitric oxide reductases" @default.
- W3186751435 cites W1523229642 @default.
- W3186751435 cites W1537911503 @default.
- W3186751435 cites W1538021183 @default.
- W3186751435 cites W1592375558 @default.
- W3186751435 cites W1964893634 @default.
- W3186751435 cites W1968189006 @default.
- W3186751435 cites W1970280824 @default.
- W3186751435 cites W1971581339 @default.
- W3186751435 cites W1973668364 @default.
- W3186751435 cites W1974023611 @default.
- W3186751435 cites W1976140063 @default.
- W3186751435 cites W1976599798 @default.
- W3186751435 cites W1981366516 @default.
- W3186751435 cites W1981704948 @default.
- W3186751435 cites W1982411701 @default.
- W3186751435 cites W1983623091 @default.
- W3186751435 cites W1985221224 @default.
- W3186751435 cites W1988713135 @default.
- W3186751435 cites W1988841674 @default.
- W3186751435 cites W1990804384 @default.
- W3186751435 cites W1991324143 @default.
- W3186751435 cites W1991330623 @default.
- W3186751435 cites W1993778560 @default.
- W3186751435 cites W1995418515 @default.
- W3186751435 cites W2003006828 @default.
- W3186751435 cites W2003811454 @default.
- W3186751435 cites W2005840432 @default.
- W3186751435 cites W2007891637 @default.
- W3186751435 cites W2010970217 @default.
- W3186751435 cites W2015407072 @default.
- W3186751435 cites W2020612562 @default.
- W3186751435 cites W2023673526 @default.
- W3186751435 cites W2026157436 @default.
- W3186751435 cites W2026336405 @default.
- W3186751435 cites W2026829122 @default.
- W3186751435 cites W2026856365 @default.
- W3186751435 cites W2028516053 @default.
- W3186751435 cites W2030249448 @default.
- W3186751435 cites W2032707446 @default.
- W3186751435 cites W2034672440 @default.
- W3186751435 cites W2038899168 @default.
- W3186751435 cites W2039774954 @default.
- W3186751435 cites W2041867750 @default.
- W3186751435 cites W2042545763 @default.
- W3186751435 cites W2043119089 @default.
- W3186751435 cites W2045734345 @default.
- W3186751435 cites W2046107732 @default.
- W3186751435 cites W2046176446 @default.
- W3186751435 cites W2046654873 @default.
- W3186751435 cites W2057713873 @default.
- W3186751435 cites W2059145970 @default.
- W3186751435 cites W2061078634 @default.
- W3186751435 cites W2061746072 @default.
- W3186751435 cites W2063021162 @default.
- W3186751435 cites W2063680573 @default.
- W3186751435 cites W2069116750 @default.
- W3186751435 cites W2073706626 @default.
- W3186751435 cites W2073876100 @default.
- W3186751435 cites W2074335496 @default.
- W3186751435 cites W2078160714 @default.
- W3186751435 cites W2081447694 @default.
- W3186751435 cites W2081760113 @default.
- W3186751435 cites W2087479881 @default.
- W3186751435 cites W2088566920 @default.
- W3186751435 cites W2092711337 @default.
- W3186751435 cites W2092920070 @default.
- W3186751435 cites W2113130764 @default.
- W3186751435 cites W2116733527 @default.
- W3186751435 cites W2117216625 @default.
- W3186751435 cites W2119556702 @default.
- W3186751435 cites W2120620942 @default.
- W3186751435 cites W2121157591 @default.
- W3186751435 cites W2123340625 @default.
- W3186751435 cites W2131351657 @default.
- W3186751435 cites W2141610173 @default.
- W3186751435 cites W2149200346 @default.
- W3186751435 cites W2161976471 @default.
- W3186751435 cites W2171480404 @default.
- W3186751435 cites W2281353804 @default.
- W3186751435 cites W2294180076 @default.
- W3186751435 cites W2310168954 @default.
- W3186751435 cites W2312190143 @default.
- W3186751435 cites W2315353461 @default.
- W3186751435 cites W2317117654 @default.
- W3186751435 cites W2322619615 @default.
- W3186751435 cites W2322911121 @default.
- W3186751435 cites W2324051144 @default.
- W3186751435 cites W2326013059 @default.
- W3186751435 cites W2326096935 @default.
- W3186751435 cites W2326476509 @default.