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- W3186804928 abstract "The detection of enantiopurity for small sample quantities is crucial, particularly in the pharmaceutical industry; however, existing methodologies rely on specific chiral recognition elements, or complex optical systems, limiting its utility. A nanoscale chirality sensor, for continuously monitoring molecular chirality using an electric circuit readout, is presented. This device design represents an alternative real-time scalable approach for chiral recognition of small quantity samples (less than 103 adsorbed molecules). The active device component relies on a gold nanofloret hybrid structure, i.e., a high aspect ratio semiconductor–metal hybrid nanosystem in which a SiGe nanowire tip is selectively decorated with a gold metallic cap. The tip mechanically touches a counter electrode to generate a nanojunction, and upon exposure to molecules, a metal–molecule–metal junction is formed. Adsorption of chiral molecules at the gold tip induces chirality in the localized plasmonic resonance at the electrode–tip junction and manifests in an enantiospecific current response." @default.
- W3186804928 created "2021-08-02" @default.
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- W3186804928 date "2021-07-23" @default.
- W3186804928 modified "2023-10-12" @default.
- W3186804928 title "Chirality Nanosensor with Direct Electric Readout by Coupling of Nanofloret Localized Plasmons with Electronic Transport" @default.
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- W3186804928 doi "https://doi.org/10.1021/acs.nanolett.1c01539" @default.
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