Matches in SemOpenAlex for { <https://semopenalex.org/work/W3186822322> ?p ?o ?g. }
- W3186822322 endingPage "4408" @default.
- W3186822322 startingPage "4408" @default.
- W3186822322 abstract "The aim of this research is to obtain new data about the complexation between β-cyclodextrin (β-CD) and benzoic acid (BA) as a model reaction of the complex formation of hydrophobic molecules with cyclodextrins (CDs) in various media. This research may help developing cyclodextrin-based pharmaceutical formulations through the choice of the appropriate solvent mixture that may be employed in the industrial application aiming to control the reactions/processes in liquid phase. In this paper, NMR results for the molecular complex formation between BA and β-CD ([BA⊂β-CD]) in D2O-DMSO-d6 and in D2O-EtOH have shown that the stability of the complex in the H2O-DMSO-d6 varies within the experimental error, while decreases in H2O-EtOH. Changes in the Gibbs energy of BA resolvation in water and water–dimethylsulfoxide mixtures have been obtained and have been used in the analysis of the reagent solvation contributions into the Gibbs energy changes of the [BA⊂β-CD] molecular complex formation. Quantum chemical calculations of the interaction energy between β-CD and BA as well as the structure of the [BA⊂β-CD] complex and the energy of β-CD and BA interaction in vacuum and in the medium of water, methanol and dimethylsulfoxide solvents are carried out. The stability of [BA⊂β-CD] complex in H2O-EtOH and H2O-DMSO solvents, obtained by different methods, are compared. The thermodynamic parameters of the [BA⊂β-CD] molecular complexation as well as the reagent solvation contributions in H2O-EtOH and H2O-DMSO mixtures were analyzed by the solvation-thermodynamic approach." @default.
- W3186822322 created "2021-08-02" @default.
- W3186822322 creator A5002319409 @default.
- W3186822322 creator A5005435129 @default.
- W3186822322 creator A5013129672 @default.
- W3186822322 creator A5017274309 @default.
- W3186822322 creator A5019418212 @default.
- W3186822322 creator A5024678577 @default.
- W3186822322 creator A5038153849 @default.
- W3186822322 creator A5039305820 @default.
- W3186822322 creator A5045317223 @default.
- W3186822322 creator A5064614347 @default.
- W3186822322 creator A5068862723 @default.
- W3186822322 creator A5070413261 @default.
- W3186822322 creator A5080432127 @default.
- W3186822322 creator A5083131811 @default.
- W3186822322 creator A5087458677 @default.
- W3186822322 date "2021-07-21" @default.
- W3186822322 modified "2023-10-18" @default.
- W3186822322 title "Complexation of Cyclodextrins with Benzoic Acid in Water-Organic Solvents: A Solvation-Thermodynamic Approach" @default.
- W3186822322 cites W1512952842 @default.
- W3186822322 cites W1524731622 @default.
- W3186822322 cites W1818696188 @default.
- W3186822322 cites W1978752364 @default.
- W3186822322 cites W1987263958 @default.
- W3186822322 cites W1988863366 @default.
- W3186822322 cites W1992267497 @default.
- W3186822322 cites W1994908899 @default.
- W3186822322 cites W1997649156 @default.
- W3186822322 cites W2001296842 @default.
- W3186822322 cites W2005807914 @default.
- W3186822322 cites W2022208906 @default.
- W3186822322 cites W2022861012 @default.
- W3186822322 cites W2027703351 @default.
- W3186822322 cites W2028171488 @default.
- W3186822322 cites W2028909872 @default.
- W3186822322 cites W2030112831 @default.
- W3186822322 cites W2030834020 @default.
- W3186822322 cites W2040521335 @default.
- W3186822322 cites W2043762028 @default.
- W3186822322 cites W2050534952 @default.
- W3186822322 cites W2052624695 @default.
- W3186822322 cites W2053375021 @default.
- W3186822322 cites W2057345633 @default.
- W3186822322 cites W2058765319 @default.
- W3186822322 cites W2065037843 @default.
- W3186822322 cites W2067763444 @default.
- W3186822322 cites W2071031209 @default.
- W3186822322 cites W2071418051 @default.
- W3186822322 cites W2073440492 @default.
- W3186822322 cites W2080681717 @default.
- W3186822322 cites W2083248314 @default.
- W3186822322 cites W2083334732 @default.
- W3186822322 cites W2084660111 @default.
- W3186822322 cites W2086589276 @default.
- W3186822322 cites W2089811710 @default.
- W3186822322 cites W2092924706 @default.
- W3186822322 cites W2139131481 @default.
- W3186822322 cites W2154423411 @default.
- W3186822322 cites W2265242384 @default.
- W3186822322 cites W2296799924 @default.
- W3186822322 cites W2298016861 @default.
- W3186822322 cites W2505647965 @default.
- W3186822322 cites W2509060679 @default.
- W3186822322 cites W2605801743 @default.
- W3186822322 cites W2609462311 @default.
- W3186822322 cites W2900711231 @default.
- W3186822322 cites W2911835207 @default.
- W3186822322 cites W2911997094 @default.
- W3186822322 cites W2920715326 @default.
- W3186822322 cites W3006234984 @default.
- W3186822322 cites W3020097213 @default.
- W3186822322 cites W3029506724 @default.
- W3186822322 cites W3034440326 @default.
- W3186822322 cites W3087171576 @default.
- W3186822322 cites W3090980694 @default.
- W3186822322 cites W3092299553 @default.
- W3186822322 cites W3108879311 @default.
- W3186822322 cites W3197886297 @default.
- W3186822322 cites W39136309 @default.
- W3186822322 doi "https://doi.org/10.3390/molecules26154408" @default.
- W3186822322 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8348358" @default.
- W3186822322 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34361559" @default.
- W3186822322 hasPublicationYear "2021" @default.
- W3186822322 type Work @default.
- W3186822322 sameAs 3186822322 @default.
- W3186822322 citedByCount "7" @default.
- W3186822322 countsByYear W31868223222022 @default.
- W3186822322 countsByYear W31868223222023 @default.
- W3186822322 crossrefType "journal-article" @default.
- W3186822322 hasAuthorship W3186822322A5002319409 @default.
- W3186822322 hasAuthorship W3186822322A5005435129 @default.
- W3186822322 hasAuthorship W3186822322A5013129672 @default.
- W3186822322 hasAuthorship W3186822322A5017274309 @default.
- W3186822322 hasAuthorship W3186822322A5019418212 @default.
- W3186822322 hasAuthorship W3186822322A5024678577 @default.
- W3186822322 hasAuthorship W3186822322A5038153849 @default.
- W3186822322 hasAuthorship W3186822322A5039305820 @default.