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- W3187090892 abstract "The nucleophilic reactions of piperidine with ionized phenyl salicylate (PSa ‒ ) reveal a nonlinear decrease with the increase in concentration of didodecyldimethylammonium bromide (DDABr) micelles (D n ) at 35 °C and in the absence as well as presence of constant [NaBr]. The plots of pseudo-first-order rate constants ( k obs ) versus [D n ]) have been explained quantitatively in terms of pseudophase micellar model. Such a data treatment gives DDABr micellar binding constant ( K S ) of PSa − . The effects of [NaBr] upon K S is explained with an empirical relationship which provides an empirical constant ( K Br/S where S = PSa − ). The magnitude of K Br/S is the measure of the ability of ion Br − to expel the co-ion PSa − from the cationic micellar pseudophase to the bulk aqueous phase. The origin of the large catalytic effect of DDABr/NaBr/H 2 O nanoparticles on the rate of piperidinolysis of PSa − is described in terms of plausible physicochemical causes." @default.
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- W3187090892 date "2020-10-12" @default.
- W3187090892 modified "2023-09-22" @default.
- W3187090892 title "Effect of [NaBr] on the rate of intramolecular base-assisted piperidinolysis of ionized phenyl salicylate in the presence of double-tail cationic surfactant aggregates: DDABr/NaBr/H 2 O nanoparticles catalysis" @default.
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