Matches in SemOpenAlex for { <https://semopenalex.org/work/W3187108130> ?p ?o ?g. }
- W3187108130 endingPage "39270" @default.
- W3187108130 startingPage "39257" @default.
- W3187108130 abstract "Herein, we report the design of styrene-based poly(ethylene oxide) (PEO) side-chain block copolymers featuring a microphase separation and their application as solid polymer electrolytes in high-voltage lithium-metal batteries. A straightforward synthesis was established, overcoming typical drawbacks of PEO block copolymers prepared by anionic polymerization or ester-based PEO side-chain copolymers. Both the PEO side-chain length and the LiTFSI content were varied, and the underlying relationships were elucidated in view of polymer compositions with high ionic conductivity. Subsequently, a selected composition was subjected to further analyses, including phase-separated morphology, providing not only excellent self-standing films with intrinsic mechanical stability but also the ability to suppress lithium dendrite growth as well as good flexibility, wettability, and good contacts with the electrodes. Furthermore, good thermal and electrochemical stability was demonstrated. To do so, linear sweep and cyclic voltammetry, lithium plating/stripping tests, and galvanostatic overcharging using high-voltage cathodes were conducted, demonstrating stable lithium-metal interfaces and a high oxidative stability of around 4.75 V. Consequently, cycling of Li||NMC622 cells did not exhibit commonly observed rapid cell failure or voltage noise associated with PEO-based electrolytes in Li||NMC622 cells, attributed to the high mechanical stability. A comprehensive view is provided, highlighting that the combination of PEO and high-voltage cathodes is not impossible per se." @default.
- W3187108130 created "2021-08-16" @default.
- W3187108130 creator A5000203192 @default.
- W3187108130 creator A5000367725 @default.
- W3187108130 creator A5027398832 @default.
- W3187108130 creator A5027928367 @default.
- W3187108130 creator A5038293920 @default.
- W3187108130 creator A5040612799 @default.
- W3187108130 creator A5074095330 @default.
- W3187108130 creator A5081732198 @default.
- W3187108130 creator A5082858164 @default.
- W3187108130 date "2021-08-10" @default.
- W3187108130 modified "2023-10-06" @default.
- W3187108130 title "Styrene-Based Poly(ethylene oxide) Side-Chain Block Copolymers as Solid Polymer Electrolytes for High-Voltage Lithium-Metal Batteries" @default.
- W3187108130 cites W1585306775 @default.
- W3187108130 cites W1901394093 @default.
- W3187108130 cites W1969530877 @default.
- W3187108130 cites W1981950273 @default.
- W3187108130 cites W1996879303 @default.
- W3187108130 cites W2000576000 @default.
- W3187108130 cites W2019496427 @default.
- W3187108130 cites W2026248075 @default.
- W3187108130 cites W2038064928 @default.
- W3187108130 cites W2039772638 @default.
- W3187108130 cites W2048419315 @default.
- W3187108130 cites W2052551423 @default.
- W3187108130 cites W2054896915 @default.
- W3187108130 cites W2056189120 @default.
- W3187108130 cites W2060015544 @default.
- W3187108130 cites W2078099811 @default.
- W3187108130 cites W2082866588 @default.
- W3187108130 cites W2089403233 @default.
- W3187108130 cites W2110395021 @default.
- W3187108130 cites W2150661114 @default.
- W3187108130 cites W2153137852 @default.
- W3187108130 cites W2169722766 @default.
- W3187108130 cites W2282324288 @default.
- W3187108130 cites W2317402284 @default.
- W3187108130 cites W2322559537 @default.
- W3187108130 cites W2346602187 @default.
- W3187108130 cites W2509062966 @default.
- W3187108130 cites W2513747533 @default.
- W3187108130 cites W2514130035 @default.
- W3187108130 cites W2559148811 @default.
- W3187108130 cites W2566353816 @default.
- W3187108130 cites W2574041145 @default.
- W3187108130 cites W2724543210 @default.
- W3187108130 cites W2733237701 @default.
- W3187108130 cites W2735549117 @default.
- W3187108130 cites W2742075475 @default.
- W3187108130 cites W2754088550 @default.
- W3187108130 cites W2766034019 @default.
- W3187108130 cites W2788752125 @default.
- W3187108130 cites W2790191327 @default.
- W3187108130 cites W2790599553 @default.
- W3187108130 cites W2790928926 @default.
- W3187108130 cites W2794189429 @default.
- W3187108130 cites W2796223544 @default.
- W3187108130 cites W2808049910 @default.
- W3187108130 cites W2884414805 @default.
- W3187108130 cites W2887102393 @default.
- W3187108130 cites W2910730543 @default.
- W3187108130 cites W2922132902 @default.
- W3187108130 cites W2934261307 @default.
- W3187108130 cites W2943180897 @default.
- W3187108130 cites W2947611771 @default.
- W3187108130 cites W3005516162 @default.
- W3187108130 cites W3009325453 @default.
- W3187108130 cites W3011278199 @default.
- W3187108130 cites W3033106394 @default.
- W3187108130 cites W3038358171 @default.
- W3187108130 cites W3042464537 @default.
- W3187108130 cites W3046115983 @default.
- W3187108130 cites W3048330539 @default.
- W3187108130 cites W3050728277 @default.
- W3187108130 cites W3080472559 @default.
- W3187108130 cites W3111745085 @default.
- W3187108130 cites W3112839340 @default.
- W3187108130 cites W3118606465 @default.
- W3187108130 cites W3127114275 @default.
- W3187108130 cites W3131187634 @default.
- W3187108130 cites W3131823143 @default.
- W3187108130 cites W3134995930 @default.
- W3187108130 cites W3180765175 @default.
- W3187108130 doi "https://doi.org/10.1021/acsami.1c08841" @default.
- W3187108130 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34374509" @default.
- W3187108130 hasPublicationYear "2021" @default.
- W3187108130 type Work @default.
- W3187108130 sameAs 3187108130 @default.
- W3187108130 citedByCount "29" @default.
- W3187108130 countsByYear W31871081302021 @default.
- W3187108130 countsByYear W31871081302022 @default.
- W3187108130 countsByYear W31871081302023 @default.
- W3187108130 crossrefType "journal-article" @default.
- W3187108130 hasAuthorship W3187108130A5000203192 @default.
- W3187108130 hasAuthorship W3187108130A5000367725 @default.
- W3187108130 hasAuthorship W3187108130A5027398832 @default.
- W3187108130 hasAuthorship W3187108130A5027928367 @default.