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• W3187446781 abstract "A new catalytic asymmetric formal cross dehydrogenative coupling process for the construction of all-aryl quaternary stereocenters is disclosed, which provides access to rarely explored chiral tetraarylmethanes with excellent enantioselectivity. The suitable oxidation conditions and the hydrogen-bond-based organocatalysis have enabled efficient intermolecular C-C bond formation in an overwhelmingly crowded environment under mild conditions. para-Quinone methides bearing an ortho-directing group serve as the key intermediate. The precise loading of DDQ is critical to the high enantioselectivity. The chiral products have also been demonstrated as promising antiviral agents." @default.
• W3187446781 created "2021-08-16" @default.
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• W3187446781 date "2021-01-01" @default.
• W3187446781 modified "2023-10-15" @default.
• W3187446781 title "Organocatalytic asymmetric formal oxidative coupling for the construction of all-aryl quaternary stereocenters" @default.
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• W3187446781 doi "https://doi.org/10.1039/d1sc03324g" @default.
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• W3187446781 hasPublicationYear "2021" @default.
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