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- W3187491331 abstract "It is extremely difficult to anticipate the structure and the stereochemistry of a complex, particularly when the ligand is flexible and the metal node adopts diverse coordination numbers. When trivalent lanthanides (LnIII) and enantiopure amino acid ligands are utilized as building blocks, self-assembly sometimes yields rare chiral polynuclear structures. In this study, an enantiopure carboxyl-functionalized amino acid-based ligand with C3 symmetry reacts with lanthanum cations to give a homochiral porous coordination cage, (Δ/Λ)12-PCC-57. The dodecanuclear lanthanide cage has an unprecedented octahedral cage-in-cage framework. During the self-assembly, the chirality is transferred from the enantiopure ligand and fixed by the binuclear lanthanide cluster to give 12 metal centers that have either Δ or Λ homochiral stereochemistry. The cage exhibits excellent enantioselective separation of racemic alcohols, 2,3-dihydroquinazolinones, and multiple commercially available drugs. This finding exhibits a rare example of a multinuclear lanthanide complex with a dual-walled topology and homochirality. The highly ordered self-assembly and self-sorting of flexible amino acids and lanthanides shed light on the chiral transformation between different complicated artificial systems that mimic natural enzymes." @default.
- W3187491331 created "2021-08-16" @default.
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- W3187491331 date "2021-08-03" @default.
- W3187491331 modified "2023-10-18" @default.
- W3187491331 title "Homochiral Dodecanuclear Lanthanide “Cage in Cage” for Enantioselective Separation" @default.
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- W3187491331 doi "https://doi.org/10.1021/jacs.1c03652" @default.
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- W3187491331 hasPublicationYear "2021" @default.
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