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• W3187566311 abstract "Liquid-phase transmission electron microscopy (LP-TEM) enables real-time imaging of nanoparticle self-assembly, formation, and etching with single nanometer resolution. Despite the importance of organic nanoparticle capping ligands in these processes, the effect of electron beam irradiation on surface-bound and soluble capping ligands during LP-TEM imaging has not been investigated. Here, we use correlative LP-TEM and fluorescence microscopy (FM) to demonstrate that polymeric nanoparticle ligands undergo competing crosslinking and chain scission reactions that nonmonotonically modify ligand coverage over time. Branched polyethylenimine (BPEI)-coated silver nanoparticles were imaged with dose-controlled LP-TEM followed by labeling their primary amine groups with fluorophores to visualize the local thickness of adsorbed capping ligands. FM images showed that free ligands crosslinked in the LP-TEM image area over imaging times of tens of seconds, enhancing local capping ligand coverage on nanoparticles and silicon nitride membranes. Nanoparticle surface ligands underwent chain scission over irradiation times of minutes to tens of minutes, which depleted surface ligands from the nanoparticle and silicon nitride surface. Conversely, solutions of only soluble capping ligand underwent successive crosslinking reactions with no chain scission, suggesting that nanoparticles enhanced the chain scission reactions by acting as radiolysis hotspots. The addition of a hydroxyl radical scavenger, tert-butanol, eliminated chain scission reactions and slowed the progression of crosslinking reactions. These experiments have important implications for performing controlled and reproducible LP-TEM nanoparticle imaging as they demonstrate that the electron beam can significantly alter ligand coverage on nanoparticles in a nonintuitive manner. They emphasize the need to understand and control the electron beam radiation chemistry of a given sample to avoid significant perturbations to the nanoparticle capping ligand chemistry, which are invisible in electron micrographs." @default.
• W3187566311 created "2021-08-16" @default.
• W3187566311 creator A5035322817 @default.
• W3187566311 creator A5055900838 @default.
• W3187566311 creator A5061538019 @default.
• W3187566311 date "2021-08-02" @default.
• W3187566311 modified "2023-10-17" @default.
• W3187566311 title "Revealing Reactions between the Electron Beam and Nanoparticle Capping Ligands with Correlative Fluorescence and Liquid-Phase Electron Microscopy" @default.
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• W3187566311 cites W2011549392 @default.
• W3187566311 cites W2015081494 @default.
• W3187566311 cites W2015090882 @default.
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• W3187566311 cites W2022628102 @default.
• W3187566311 cites W2031004957 @default.
• W3187566311 cites W2042926990 @default.
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• W3187566311 cites W2338584008 @default.
• W3187566311 cites W2341174363 @default.
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• W3187566311 doi "https://doi.org/10.1021/acsami.1c10957" @default.
• W3187566311 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34338503" @default.
• W3187566311 hasPublicationYear "2021" @default.
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