FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3187687574> ?p ?o ?g. }

• W3187687574 endingPage "102907" @default.
• W3187687574 startingPage "102907" @default.
• W3187687574 abstract "This paper deals with structural (in-situ XRD) and electrochemical characterization of high-voltage lithium-ion cathode materials LiMn2O4 (LMO), LiNi0.5Mn1.5O4 (LNMO), and LiCr0.1Ni0.4Mn1.5O4 (LCNMO) prepared by solid-state synthesis. Structural in-situ X-ray diffraction spectra were measured by an affordable Rigaku diffractometer. Our synthesis route produced the samples with similar morphologies where the average particle sizes were 1.11 µm and 1.46 µm for LNMO and LCNMO respectively. Results of the Rietveld analysis brought detailed insight into two-phase structure transitions for LMO and three-phase transitions for LNMO and LCNMO. XRD study revealed differences in the structural behavior of LMO and LNMO prepared by solid-state synthesis compared to the results of other authors using the sol-gel synthesis route. In the case of chromium-doped LNMO, our results indicate ability of the chromium metal to effectively reduce Mn3+ content while the ordering of the structure increases. Chromium doping also promotes a larger lattice parameter in a fully delithiated state than in the case of undoped LNMO. Therefore, lowering of the volume changes was observed and faster phase II/III transition taking place, when Ni3+/Ni4+ redox pair was oxidized, was also identified. Cr doping of LNMO also promotes the reaching the lattice parameters of phases in both phase transitions and thus could reduce the internal stress of active material under high C-rate cycling. Results thus suggested that chromium doping can improve the stability of the inner structure and performance at higher charging C-rates even though the structure goes through a three-phase region during charging as undoped LNMO. The evaluation of diffusion coefficients of Cr-doped LNMO revealed increased diffusivity in a full discharge state and as the cathode underwent the cycling the differences in diffusivity seemed to be more pronounced." @default.
• W3187687574 created "2021-08-16" @default.
• W3187687574 creator A5025747926 @default.
• W3187687574 creator A5042862639 @default.
• W3187687574 creator A5078486206 @default.
• W3187687574 creator A5079720258 @default.
• W3187687574 creator A5084121507 @default.
• W3187687574 creator A5086522714 @default.
• W3187687574 date "2021-09-01" @default.
• W3187687574 modified "2023-10-16" @default.
• W3187687574 title "In-situ XRD study of a Chromium doped LiNi0.5Mn1.5O4 cathode for Li-ion battery" @default.
• W3187687574 cites W1907281686 @default.
• W3187687574 cites W1934145418 @default.
• W3187687574 cites W1966525852 @default.
• W3187687574 cites W1977594029 @default.
• W3187687574 cites W2007829965 @default.
• W3187687574 cites W2034105980 @default.
• W3187687574 cites W2035479011 @default.
• W3187687574 cites W2038059801 @default.
• W3187687574 cites W2052362608 @default.
• W3187687574 cites W2075069270 @default.
• W3187687574 cites W2076569587 @default.
• W3187687574 cites W2077330355 @default.
• W3187687574 cites W2078216324 @default.
• W3187687574 cites W2080588679 @default.
• W3187687574 cites W2086091278 @default.
• W3187687574 cites W2152510783 @default.
• W3187687574 cites W2330519294 @default.
• W3187687574 cites W2330929086 @default.
• W3187687574 cites W2412982718 @default.
• W3187687574 cites W2510424055 @default.
• W3187687574 cites W2569170848 @default.
• W3187687574 cites W2735091832 @default.
• W3187687574 cites W2767463088 @default.
• W3187687574 cites W2773164085 @default.
• W3187687574 cites W2781958299 @default.
• W3187687574 cites W2791282487 @default.
• W3187687574 cites W2902152066 @default.
• W3187687574 cites W2906830275 @default.
• W3187687574 cites W2913257194 @default.
• W3187687574 cites W2934305678 @default.
• W3187687574 cites W2934448219 @default.
• W3187687574 cites W2953621026 @default.
• W3187687574 cites W2953694591 @default.
• W3187687574 cites W2954367702 @default.
• W3187687574 cites W2971793042 @default.
• W3187687574 cites W2972216679 @default.
• W3187687574 cites W3011256860 @default.
• W3187687574 cites W330228440 @default.
• W3187687574 doi "https://doi.org/10.1016/j.est.2021.102907" @default.
• W3187687574 hasPublicationYear "2021" @default.
• W3187687574 type Work @default.
• W3187687574 sameAs 3187687574 @default.
• W3187687574 citedByCount "12" @default.
• W3187687574 countsByYear W31876875742022 @default.
• W3187687574 countsByYear W31876875742023 @default.
• W3187687574 crossrefType "journal-article" @default.
• W3187687574 hasAuthorship W3187687574A5025747926 @default.
• W3187687574 hasAuthorship W3187687574A5042862639 @default.
• W3187687574 hasAuthorship W3187687574A5078486206 @default.
• W3187687574 hasAuthorship W3187687574A5079720258 @default.
• W3187687574 hasAuthorship W3187687574A5084121507 @default.
• W3187687574 hasAuthorship W3187687574A5086522714 @default.
• W3187687574 hasConcept C113196181 @default.
• W3187687574 hasConcept C115624301 @default.
• W3187687574 hasConcept C115645028 @default.
• W3187687574 hasConcept C121332964 @default.
• W3187687574 hasConcept C127413603 @default.
• W3187687574 hasConcept C147789679 @default.
• W3187687574 hasConcept C159985019 @default.
• W3187687574 hasConcept C163258240 @default.
• W3187687574 hasConcept C175708663 @default.
• W3187687574 hasConcept C178790620 @default.
• W3187687574 hasConcept C185592680 @default.
• W3187687574 hasConcept C191897082 @default.
• W3187687574 hasConcept C192562407 @default.
• W3187687574 hasConcept C26771246 @default.
• W3187687574 hasConcept C2778591166 @default.
• W3187687574 hasConcept C2779197387 @default.
• W3187687574 hasConcept C39546656 @default.
• W3187687574 hasConcept C42360764 @default.
• W3187687574 hasConcept C43617362 @default.
• W3187687574 hasConcept C44280652 @default.
• W3187687574 hasConcept C49040817 @default.
• W3187687574 hasConcept C49110097 @default.
• W3187687574 hasConcept C511782168 @default.
• W3187687574 hasConcept C544153396 @default.
• W3187687574 hasConcept C555008776 @default.
• W3187687574 hasConcept C57863236 @default.
• W3187687574 hasConcept C8010536 @default.
• W3187687574 hasConcept C97355855 @default.
• W3187687574 hasConceptScore W3187687574C113196181 @default.
• W3187687574 hasConceptScore W3187687574C115624301 @default.
• W3187687574 hasConceptScore W3187687574C115645028 @default.
• W3187687574 hasConceptScore W3187687574C121332964 @default.
• W3187687574 hasConceptScore W3187687574C127413603 @default.
• W3187687574 hasConceptScore W3187687574C147789679 @default.
• W3187687574 hasConceptScore W3187687574C159985019 @default.

• next