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• W3188375692 abstract "Abstract Leaching experiments were performed in calcium aluminate slag with a high-sodium carbonate adaptation of the Pedersen process. A theoretical thermodynamic study of the pregnant leaching solution was conducted to specify the thermodynamically favored species that exist within. Using the HSC 9.0 software, a carbonation process simulation (neutralization of the aluminate solution with CO 2 gas) was simulated. Laboratory carbonation experiments were conducted to verify the theoretical predictions. According to the thermodynamic study, at temperatures below 50 °C gibbsite precipitates in the first stages of carbonation and then is transformed to dawsonite. Temperatures over 65 °C favor the direct precipitation of dawsonite. The same route (thermodynamic analysis, carbonation simulation, and experimental verification) was followed by a synthetic solution containing lower amount of sodium carbonate to prove that dawsonite precipitation occurred as a result of the high free carbonate content, to investigate the effect of temperature and to precipitate alumina hydrate phases. Graphical Abstract" @default.
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• W3188375692 date "2021-07-29" @default.
• W3188375692 modified "2023-09-25" @default.
• W3188375692 title "Parameters Affecting the Precipitation of Al Phases from Aluminate Solutions of the Pedersen Process: The Effect of Carbonate Content" @default.
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• W3188375692 doi "https://doi.org/10.1007/s40831-021-00403-w" @default.
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