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- W3188999931 abstract "The dark reaction between hydrogen peroxide and a pure dilute aqueous solution of potassium ferrocyanide has been critically examined. The experiments described in the paper lead to the conclusion that potassium aquopentacyanoferrite produced as a substitution product in very minute concentration in aqueous ferrocyanide in the dark reacts with hydrogen peroxide resulting in the measured dark reaction. Aged solutions of ferrocyanide, as well as pre-heated and pre-illuminated solutions used sometime after treatment show a distinctly lower rate of peroxide decomposition. This diminished reactivity towards hydrogen peroxide appears to be due to the partial decomposition of the aquo-complex salt by heat, prolonged exposure to light and ageing. The marked photochemical after-effect observed in the pre-insolated mixture of hydrogen peroxide and potassium ferrocyanide has been studied in detail with varying periods of pre-illumination of the reaction mixture. It is found that the greater the period of pre-illumination of the mixture, the greater is the photochemical after-effect within the concentration limits of reactants used in the experiments." @default.
- W3188999931 created "2021-08-16" @default.
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- W3188999931 date "1952-10-01" @default.
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- W3188999931 title "Photochemical after-effect in H 2 O 2 -K 4 Fe(CN) 6 reaction" @default.
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