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- W3189204089 abstract "We developed a convenient method for fabricating thin acrylate polycationic films as a substrate for electrostatic deposition of colloidal silver nanoplates allowing their parallel UV–vis spectroscopy and TEM examination. The deposition rate in the initial diffusion-limited regime is proportional to the molar concentration of nanoplates in colloidal solution and almost independent of the surface zeta potential of polycationic film. Switching to the adsorption-limited regime, the maximum 24 h surface coverage of nanoplates depends linearly on the surface zeta potential and is independent of their molar concentration. To unveil the deposition kinetics, we developed a simple ab initio model of the two-dimensional adsorption of hard and soft disks based on the random sequential adsorption algorithm involving the principle of effective exclusion radius. The Monte Carlo simulation gives a good approximation of the experimental kinetic curves when the effective exclusion radius squared is inversely proportional to the substrate surface zeta potential." @default.
- W3189204089 created "2021-08-16" @default.
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- W3189204089 date "2021-08-05" @default.
- W3189204089 modified "2023-10-14" @default.
- W3189204089 title "Electrostatic Deposition Kinetics of Colloidal Silver Nanoplates onto Optically and E-Beam Transparent Water-Insoluble Polycationic Films" @default.
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- W3189204089 doi "https://doi.org/10.1021/acs.jpcc.1c05404" @default.
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