Matches in SemOpenAlex for { <https://semopenalex.org/work/W3189440082> ?p ?o ?g. }
- W3189440082 endingPage "10404" @default.
- W3189440082 startingPage "10394" @default.
- W3189440082 abstract "We report the synthesis of bimetallic Pd(I) and Pd(II) complexes with bidentate 2-phosphinoimidazole ligands and their catalytic activity to generate substituted naphthalenes. This process involves the coupling of an aryl iodide and 2 equiv of a ketone via sequential ketone α-arylation and then annulation to generate disubstituted and tetrasubstituted naphthalenes in a regioselective manner. Excellent substrate scope for both aryl iodide and ketone partners is demonstrated, including that for heteroaryl iodides. Bimetallic Pd complexes are much more reactive than monometallic Pd catalysts in this transformation. Density functional theory calculations, isotope effect experiments, and substrate competition experiments were used to examine bimetallic mechanisms, reactivity, and selectivity." @default.
- W3189440082 created "2021-08-16" @default.
- W3189440082 creator A5003447327 @default.
- W3189440082 creator A5017922766 @default.
- W3189440082 creator A5018203250 @default.
- W3189440082 creator A5024304690 @default.
- W3189440082 creator A5036654374 @default.
- W3189440082 creator A5040583443 @default.
- W3189440082 creator A5068267120 @default.
- W3189440082 creator A5078005133 @default.
- W3189440082 creator A5082464150 @default.
- W3189440082 creator A5085798223 @default.
- W3189440082 creator A5086726463 @default.
- W3189440082 creator A5088532730 @default.
- W3189440082 date "2021-08-05" @default.
- W3189440082 modified "2023-10-16" @default.
- W3189440082 title "Experiment and Theory of Bimetallic Pd-Catalyzed α-Arylation and Annulation for Naphthalene Synthesis" @default.
- W3189440082 cites W1967562883 @default.
- W3189440082 cites W2011215428 @default.
- W3189440082 cites W2023630158 @default.
- W3189440082 cites W2037888438 @default.
- W3189440082 cites W2055975983 @default.
- W3189440082 cites W2068633288 @default.
- W3189440082 cites W2069348739 @default.
- W3189440082 cites W2070542379 @default.
- W3189440082 cites W2074888123 @default.
- W3189440082 cites W2077818578 @default.
- W3189440082 cites W2083333424 @default.
- W3189440082 cites W2088943937 @default.
- W3189440082 cites W2099531933 @default.
- W3189440082 cites W2105249240 @default.
- W3189440082 cites W2120204579 @default.
- W3189440082 cites W2121237359 @default.
- W3189440082 cites W2122480383 @default.
- W3189440082 cites W2150697053 @default.
- W3189440082 cites W2150805674 @default.
- W3189440082 cites W2151245295 @default.
- W3189440082 cites W2151416474 @default.
- W3189440082 cites W2169508484 @default.
- W3189440082 cites W2269503844 @default.
- W3189440082 cites W2285034312 @default.
- W3189440082 cites W2330357558 @default.
- W3189440082 cites W2512834146 @default.
- W3189440082 cites W2559821241 @default.
- W3189440082 cites W2569672999 @default.
- W3189440082 cites W2575724262 @default.
- W3189440082 cites W2596992844 @default.
- W3189440082 cites W2615132804 @default.
- W3189440082 cites W2746382135 @default.
- W3189440082 cites W2766836816 @default.
- W3189440082 cites W2767448496 @default.
- W3189440082 cites W2783041947 @default.
- W3189440082 cites W2791017218 @default.
- W3189440082 cites W2897256745 @default.
- W3189440082 cites W2912772148 @default.
- W3189440082 cites W2917734609 @default.
- W3189440082 cites W2935978067 @default.
- W3189440082 cites W2943841788 @default.
- W3189440082 cites W2944380193 @default.
- W3189440082 cites W2950054292 @default.
- W3189440082 cites W2950399541 @default.
- W3189440082 cites W2951894120 @default.
- W3189440082 cites W2952068096 @default.
- W3189440082 cites W2952419475 @default.
- W3189440082 cites W2954855618 @default.
- W3189440082 cites W2989640951 @default.
- W3189440082 cites W3006101222 @default.
- W3189440082 cites W3007604147 @default.
- W3189440082 cites W3028465068 @default.
- W3189440082 cites W3036753984 @default.
- W3189440082 cites W3092868473 @default.
- W3189440082 cites W650905102 @default.
- W3189440082 cites W2061994745 @default.
- W3189440082 doi "https://doi.org/10.1021/acscatal.1c02731" @default.
- W3189440082 hasPublicationYear "2021" @default.
- W3189440082 type Work @default.
- W3189440082 sameAs 3189440082 @default.
- W3189440082 citedByCount "7" @default.
- W3189440082 countsByYear W31894400822021 @default.
- W3189440082 countsByYear W31894400822022 @default.
- W3189440082 countsByYear W31894400822023 @default.
- W3189440082 crossrefType "journal-article" @default.
- W3189440082 hasAuthorship W3189440082A5003447327 @default.
- W3189440082 hasAuthorship W3189440082A5017922766 @default.
- W3189440082 hasAuthorship W3189440082A5018203250 @default.
- W3189440082 hasAuthorship W3189440082A5024304690 @default.
- W3189440082 hasAuthorship W3189440082A5036654374 @default.
- W3189440082 hasAuthorship W3189440082A5040583443 @default.
- W3189440082 hasAuthorship W3189440082A5068267120 @default.
- W3189440082 hasAuthorship W3189440082A5078005133 @default.
- W3189440082 hasAuthorship W3189440082A5082464150 @default.
- W3189440082 hasAuthorship W3189440082A5085798223 @default.
- W3189440082 hasAuthorship W3189440082A5086726463 @default.
- W3189440082 hasAuthorship W3189440082A5088532730 @default.
- W3189440082 hasConcept C111368507 @default.
- W3189440082 hasConcept C118792377 @default.
- W3189440082 hasConcept C127313418 @default.
- W3189440082 hasConcept C142724271 @default.