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- W3189443867 endingPage "1996" @default.
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- W3189443867 abstract "Exfoliated black phosphorus (bP) embedded into a polymer is preserved from oxidation, is stable to air, light, and humidity, and can be further processed into devices without degrading its properties. Most of the examples of exfoliated bP/polymer composites involve a single polymer matrix. Herein, we report the preparation of biphasic polystyrene/poly(methyl methacrylate) (50/50 wt.%) composites containing few-layer black phosphorus (fl-bP) (0.6–1 wt.%) produced by sonicated-assisted liquid-phase exfoliation. Micro-Raman spectroscopy confirmed the integrity of fl-bP, while scanning electron microscopy evidenced the influence of fl-bP into the coalescence of polymeric phases. Furthermore, the topography of thin films analyzed by atomic force microscopy confirmed the effect of fl-bP into the PS dewetting, and the selective PS etching of thin films revealed the presence of fl-bP flakes. Finally, a block copolymer/fl-bP composite (1.2 wt.%) was prepared via in situ reversible addition–fragmentation chain transfer (RAFT) polymerization by sonication-assisted exfoliation of bP into styrene. For this sample, 31P solid-state NMR and Raman spectroscopy confirmed an excellent preservation of bP structure." @default.
- W3189443867 created "2021-08-16" @default.
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- W3189443867 date "2021-08-03" @default.
- W3189443867 modified "2023-10-16" @default.
- W3189443867 title "Dispersion of Few-Layer Black Phosphorus in Binary Polymer Blend and Block Copolymer Matrices" @default.
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- W3189443867 doi "https://doi.org/10.3390/nano11081996" @default.
- W3189443867 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8398111" @default.
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- W3189443867 hasPublicationYear "2021" @default.
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