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- W318966970 abstract "Some special features in the mechanism of autooxidation of cyclopentadienyl complexes of uranium of the composition (/eta//sup 5/-C/sub 5/H/sub 5/)/sub n/UX/sub 4-n/ (where X = C/sub 5/H/sub 5/, Cl, n-C/sub 4/H/sub 9/, or iso-C/sub 4/H/sub 9/) have been examined, including the probable routes of oxidative transformation of the cyclopentadienyl ligands. It has been shown that the conversion of cyclopentadienyl ligands during the course of the investigated process is brought about either by their intramolecular oxidation in an MOC/centered dot/O/sub 2/ complex (where MOC is the starting organometallic compound or an organometallic product of its reaction with oxygen, containing cyclopentadienyl ligands), or by reaction of this complex with cyclopentadiene liberated on oxidative degradation of the organometallic compound. Depending on the state of the coordinated oxygen, cyclopentadiene as a reagent can display the function of a conjugated diene, a CH acid, or of a hydrogen atom donor." @default.
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- W318966970 date "1989-01-01" @default.
- W318966970 modified "2023-09-27" @default.
- W318966970 title "Some problems in the mechanism of the reaction of cyclopentadienyl compounds of uranium (IV) with molecular oxygen" @default.
- W318966970 hasPublicationYear "1989" @default.
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