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- W3189731110 endingPage "13085" @default.
- W3189731110 startingPage "13051" @default.
- W3189731110 abstract "Merging hydrogen (H2) evolution with oxidative organic synthesis in a semiconductor-mediated photoredox reaction is extremely attractive because the clean H2 fuel and high-value chemicals can be coproduced under mild conditions using light as the sole energy input. Following this dual-functional photocatalytic strategy, a dreamlike reaction pathway for constructing C-C/C-X (X = C, N, O, S) bonds from abundant and readily available X-H bond-containing compounds with concomitant release of H2 can be readily fulfilled without the need of external chemical reagents, thus offering a green and fascinating organic synthetic strategy. In this review, we begin by presenting a concise overview on the general background of traditional photocatalytic H2 production and then focus on the fundamental principles of cooperative photoredox coupling of selective organic synthesis and H2 production by simultaneous utilization of photoexcited electrons and holes over semiconductor-based catalysts to meet the economic and sustainability goal. Thereafter, we put dedicated emphasis on recent key progress of cooperative photoredox coupling of H2 production and various selective organic transformations, including selective alcohol oxidation, selective methane conversion, amines oxidative coupling, oxidative cross-coupling, cyclic alkanes dehydrogenation, reforming of lignocellulosic biomass, and so on. Finally, the remaining challenges and future perspectives in this flourishing area have been critically discussed. It is anticipated that this review will provide enlightening guidance on the rational design of such dual-functional photoredox reaction system, thereby stimulating the development of economical and environmentally benign solar fuel generation and organic synthesis of value-added fine chemicals." @default.
- W3189731110 created "2021-08-16" @default.
- W3189731110 creator A5026347224 @default.
- W3189731110 creator A5035012127 @default.
- W3189731110 creator A5066033097 @default.
- W3189731110 creator A5072397552 @default.
- W3189731110 creator A5086250289 @default.
- W3189731110 date "2021-08-11" @default.
- W3189731110 modified "2023-10-17" @default.
- W3189731110 title "Cooperative Coupling of Oxidative Organic Synthesis and Hydrogen Production over Semiconductor-Based Photocatalysts" @default.
- W3189731110 cites W1750457094 @default.
- W3189731110 cites W1829643206 @default.
- W3189731110 cites W1916659016 @default.
- W3189731110 cites W1963805768 @default.
- W3189731110 cites W1964776960 @default.
- W3189731110 cites W1967548711 @default.
- W3189731110 cites W1972126758 @default.
- W3189731110 cites W1972535788 @default.
- W3189731110 cites W1972957600 @default.
- W3189731110 cites W1975500345 @default.
- W3189731110 cites W1977878401 @default.
- W3189731110 cites W1979112470 @default.
- W3189731110 cites W1979268676 @default.
- W3189731110 cites W1980225917 @default.
- W3189731110 cites W1980804014 @default.
- W3189731110 cites W1982267818 @default.
- W3189731110 cites W1982874695 @default.
- W3189731110 cites W1983319252 @default.
- W3189731110 cites W1986059979 @default.
- W3189731110 cites W1989425419 @default.
- W3189731110 cites W1990461060 @default.
- W3189731110 cites W1990550404 @default.
- W3189731110 cites W1992136391 @default.
- W3189731110 cites W1992300523 @default.
- W3189731110 cites W1992704644 @default.
- W3189731110 cites W1992910901 @default.
- W3189731110 cites W1995105845 @default.
- W3189731110 cites W1996232250 @default.
- W3189731110 cites W1996923858 @default.
- W3189731110 cites W1997719577 @default.
- W3189731110 cites W1998482049 @default.
- W3189731110 cites W2001862230 @default.
- W3189731110 cites W2002267607 @default.
- W3189731110 cites W2005015143 @default.
- W3189731110 cites W2005164040 @default.
- W3189731110 cites W2005356006 @default.
- W3189731110 cites W2009705119 @default.
- W3189731110 cites W2010939774 @default.
- W3189731110 cites W2011824715 @default.
- W3189731110 cites W2013367814 @default.
- W3189731110 cites W2015031042 @default.
- W3189731110 cites W2016913594 @default.
- W3189731110 cites W2022071849 @default.
- W3189731110 cites W2027311299 @default.
- W3189731110 cites W2029870483 @default.
- W3189731110 cites W2031793983 @default.
- W3189731110 cites W2034666139 @default.
- W3189731110 cites W2035687030 @default.
- W3189731110 cites W2037075519 @default.
- W3189731110 cites W2039475059 @default.
- W3189731110 cites W2040463862 @default.
- W3189731110 cites W2041473493 @default.
- W3189731110 cites W2042492216 @default.
- W3189731110 cites W2046045075 @default.
- W3189731110 cites W2047675270 @default.
- W3189731110 cites W2050525065 @default.
- W3189731110 cites W2052994478 @default.
- W3189731110 cites W2056052213 @default.
- W3189731110 cites W2058860627 @default.
- W3189731110 cites W2059692055 @default.
- W3189731110 cites W2060969278 @default.
- W3189731110 cites W2061273641 @default.
- W3189731110 cites W2065938331 @default.
- W3189731110 cites W2066327595 @default.
- W3189731110 cites W2067054456 @default.
- W3189731110 cites W2068908844 @default.
- W3189731110 cites W2069538178 @default.
- W3189731110 cites W2071325808 @default.
- W3189731110 cites W2073621690 @default.
- W3189731110 cites W2074996601 @default.
- W3189731110 cites W2076101422 @default.
- W3189731110 cites W2077472794 @default.
- W3189731110 cites W2078378500 @default.
- W3189731110 cites W2078468493 @default.
- W3189731110 cites W2078584844 @default.
- W3189731110 cites W2081616863 @default.
- W3189731110 cites W2085286926 @default.
- W3189731110 cites W2086848113 @default.
- W3189731110 cites W2088415878 @default.
- W3189731110 cites W2089482761 @default.
- W3189731110 cites W2089889364 @default.
- W3189731110 cites W2091298089 @default.
- W3189731110 cites W2091499914 @default.
- W3189731110 cites W2091739334 @default.
- W3189731110 cites W2093896534 @default.
- W3189731110 cites W2095451688 @default.
- W3189731110 cites W2096736391 @default.
- W3189731110 cites W2097446202 @default.