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- W3189741912 abstract "Abstract This work reports on the use of gallium aminotrisphenolate compounds as catalysts for the synthesis of cyclic carbonates from epoxides and CO 2 . The results show that they are highly active, and more so than the corresponding aluminium congeners. The catalyst system is applicable at low and elevated temperatures across a wide substrate scope including terminal, internal, multiple and fully deuterated epoxides. Applying low catalyst loadings has allowed for a TON of 344,000 to be obtained, highlighting their stability. A DFT investigation has confirmed that the gallium catalysts have lower energetic profiles compared to the aluminium congeners. Measurement of the Lewis acidity of both the gallium and aluminium aminotrisphenolate compounds using the Gutmann‐Beckett method provides the experimental proof that the gallium compounds are more Lewis acidic than their aluminium congeners. Finally, Ab‐Initio Molecular Dynamic (AIMD) simulations have investigated and quantified the dynamic behaviour of the catalytic systems, highlighting an important increase in fluxionality in some cases which helps to explain the increase in catalytic activity." @default.
- W3189741912 created "2021-08-16" @default.
- W3189741912 creator A5000945854 @default.
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- W3189741912 creator A5024754581 @default.
- W3189741912 creator A5033662883 @default.
- W3189741912 creator A5033998739 @default.
- W3189741912 date "2021-08-19" @default.
- W3189741912 modified "2023-10-16" @default.
- W3189741912 title "Catalytic Formation of Cyclic Carbonates using Gallium Aminotrisphenolate Compounds and Comparison to their Aluminium Congeners: A Combined Experimental and Computational Study" @default.
- W3189741912 cites W1531931052 @default.
- W3189741912 cites W1981111904 @default.
- W3189741912 cites W1982214939 @default.
- W3189741912 cites W1988004885 @default.
- W3189741912 cites W1988091937 @default.
- W3189741912 cites W1988165294 @default.
- W3189741912 cites W2003286577 @default.
- W3189741912 cites W2008836275 @default.
- W3189741912 cites W2017928980 @default.
- W3189741912 cites W2025201155 @default.
- W3189741912 cites W2028046413 @default.
- W3189741912 cites W2029667189 @default.
- W3189741912 cites W2035559468 @default.
- W3189741912 cites W2039293281 @default.
- W3189741912 cites W2053382073 @default.
- W3189741912 cites W2060975977 @default.
- W3189741912 cites W2064376534 @default.
- W3189741912 cites W2077451616 @default.
- W3189741912 cites W2078146328 @default.
- W3189741912 cites W2079693516 @default.
- W3189741912 cites W2079935930 @default.
- W3189741912 cites W2082755340 @default.
- W3189741912 cites W2093161659 @default.
- W3189741912 cites W2094413778 @default.
- W3189741912 cites W2096747776 @default.
- W3189741912 cites W2103247835 @default.
- W3189741912 cites W2105634484 @default.
- W3189741912 cites W2132036982 @default.
- W3189741912 cites W2132525235 @default.
- W3189741912 cites W2134933386 @default.
- W3189741912 cites W2135512249 @default.
- W3189741912 cites W2145408306 @default.
- W3189741912 cites W2150493946 @default.
- W3189741912 cites W2168248307 @default.
- W3189741912 cites W2239054427 @default.
- W3189741912 cites W2254003811 @default.
- W3189741912 cites W2313391984 @default.
- W3189741912 cites W2321463950 @default.
- W3189741912 cites W2322788072 @default.
- W3189741912 cites W2331198214 @default.
- W3189741912 cites W2418973097 @default.
- W3189741912 cites W2474294794 @default.
- W3189741912 cites W2522678158 @default.
- W3189741912 cites W2556207445 @default.
- W3189741912 cites W2559797869 @default.
- W3189741912 cites W2563248292 @default.
- W3189741912 cites W2587835084 @default.
- W3189741912 cites W2600944613 @default.
- W3189741912 cites W2607180506 @default.
- W3189741912 cites W2608505597 @default.
- W3189741912 cites W2609333415 @default.
- W3189741912 cites W2613725087 @default.
- W3189741912 cites W2733862906 @default.
- W3189741912 cites W2736744306 @default.
- W3189741912 cites W2739439285 @default.
- W3189741912 cites W2768153533 @default.
- W3189741912 cites W2786368684 @default.
- W3189741912 cites W2789023065 @default.
- W3189741912 cites W2794049694 @default.
- W3189741912 cites W2801724997 @default.
- W3189741912 cites W2807161168 @default.
- W3189741912 cites W2884754329 @default.
- W3189741912 cites W2889632453 @default.
- W3189741912 cites W2890400854 @default.
- W3189741912 cites W2908169377 @default.
- W3189741912 cites W2909395563 @default.
- W3189741912 cites W2909747996 @default.
- W3189741912 cites W2911997094 @default.
- W3189741912 cites W2917427606 @default.
- W3189741912 cites W2921501379 @default.
- W3189741912 cites W2932297636 @default.
- W3189741912 cites W2945702879 @default.
- W3189741912 cites W2946723043 @default.
- W3189741912 cites W2949760902 @default.
- W3189741912 cites W2949960177 @default.
- W3189741912 cites W2951493675 @default.
- W3189741912 cites W2953026345 @default.
- W3189741912 cites W2954545076 @default.
- W3189741912 cites W2968072283 @default.
- W3189741912 cites W2992363017 @default.
- W3189741912 cites W2999892469 @default.
- W3189741912 cites W3005633666 @default.
- W3189741912 cites W3005711490 @default.
- W3189741912 cites W3013582981 @default.
- W3189741912 cites W3021723476 @default.
- W3189741912 cites W3029910067 @default.
- W3189741912 cites W3034831210 @default.
- W3189741912 cites W3041373173 @default.