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- W3190394023 abstract "A method is proposed for predicting the substitution behavior of ternary elements (X) in B2-type intermetallic compounds (AB) having substitutional (antistructure) defects at offstoichiometric compositions. Calculations are carried out using the pseudo-ground state analysis based on the nearest-neighbor, pair-approximation. The results revealed that the site preference of X can be determined by both heat of formation and alloy concentration: X occupies A sites only in case of {delta}H{sub BX}<{delta}H{sub AB}+{delta}H{sub AX} ({delta}H{sub AB} stands for the heat of formation between A and B), X occupies B sites only in case of {delta}H{sub AX}<{delta}H{sub AB}+{delta}H{sub BX}, and in cases, X occupies both or either A and/or B sites unfilled by constituent elements depending on alloy concentration. It is shown that: in NiTi, CoTi and FeTi, most 3A-and 4A-group elements occupy Ti sites only, and most 8A-, 4B-and 5B-group elements occupy Ni, Co and Fe sites only; while in NiAl, Co, Rh etc. occupy Ni sites only, and Si occupy Al sites only. These results are in good agreement with available data in the literature. 18 refs., 6 figs., 5 tabs." @default.
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- W3190394023 date "1996-09-20" @default.
- W3190394023 modified "2023-09-24" @default.
- W3190394023 title "Prediction of substitutional behavior of ternary elements in B2 type NiTi, CoTi, FeTi and NiAl; B2 gata kinzokukan kagobutsu NiTi, CoTi, FeTi oyobi NiAl no tenka genso okikae kyodo no yosoku" @default.
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