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- W3190570036 abstract "Electrodeposited Bi, Sn and In catalysts are employed as model catalysts to investigate the nature of active sites and the influence of surface hydroxyls on the formation of formate during CO2 electroreduction (CO2RR). With SEM, XPS, in situ XRD, electrochemical measurements and DFT calculations, the active sites are Bi0, SnO and In2O3, with their affinities to hydroxyls following the trend of Bi0 < SnO < In2O3. KIE analysis and in situ ATR-IR suggest two parallel pathways for formate production, with one proceeding on hydroxylated sites involving the interaction of CO2 with hydroxyls to form bicarbonates and another one proceeding on hydroxyl-free sites involving *OCHO as the key intermediate. The participation of hydroxyl groups in CO2RR follows Bi < Sn < In depending on their affinity to hydroxyls." @default.
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- W3190570036 date "2021-12-01" @default.
- W3190570036 modified "2023-10-03" @default.
- W3190570036 title "Probing the role of surface hydroxyls for Bi, Sn and In catalysts during CO2 Reduction" @default.
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- W3190570036 doi "https://doi.org/10.1016/j.apcatb.2021.120581" @default.
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