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- W3190630379 abstract "Nowadays, the metal oxide-based composites loaded with reduced graphene oxide (rGO) nano sheets are believed to enhance both the electrochemical and dielectric properties. In this study, therefore, the effect of rGO loading contents on the calcium aluminate (CA), namely [email protected] rGO, cement composites with high dielectric and electrochemical properties is presented. [email protected] rGO composites were successfully synthesized via a simple direct mixing of CA cement with various contents of graphene oxide (GO) precursors followed by a conventional thermal reduction method. Based on XRD and Raman spectroscopy results, all prepared [email protected] rGO composites clearly confirmed both the structure of the pristine CA cement as well as the complete conversion of GO precursors to rGO after thermal reduction, and the existence of rGO nano sheets on the surface of [email protected] rGO composites. The impedance value results revealed that the enhancement of a high dielectric constant was achieved in the [email protected] rGO composites due to both typical interface polarization and the micro-capacitor of CA cement and rGO nano sheets. Meanwhile, the prepared [email protected] rGO-4 composite electrode exhibited the highest of electrochemical double-layer capacitive behavior with the specific capacitance (Csc) value of 79.33 F g−1 at 0.2 A g−1. The enhanced super-capacitive performance of [email protected] rGO composite can be improved by the synergistic effect of free electron transfer and electron diffusion between the CA cement interface and rGO nano sheets." @default.
- W3190630379 created "2021-08-16" @default.
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- W3190630379 date "2021-10-01" @default.
- W3190630379 modified "2023-09-26" @default.
- W3190630379 title "Influence of free electron charge and free extra framework anions in calcium aluminate@ rGO (CA@ rGO) cement composites with enhanced dielectric and electrochemical properties" @default.
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- W3190630379 doi "https://doi.org/10.1016/j.jtice.2021.08.007" @default.
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