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• W3190641114 abstract "The article presents the nature and  extent of the influence of nonlocal interactions in combination with segregation on the phase  composition in liquid melt of Al-In binary system. The concentration profiles in liquid Al-In  nano-alloy with spherical symmetry were calculated using previously developed method of  numerical optimization of the thermodynamic potential density. Dimensional diagram  obtained for the collapse of the liquid melt of Al-In binary system and studied their behavior  depending on the composition of the nanoparticles and the degree of nonlocal interactions. It  was established that the effect of segregation makes profitable decay in nanoscale particle  than one selection phase with an average concentration, so in nanoscale particle decay  occurs even in the area of sustainability. Cahn coefficient effects on the decay, so if it is small,  then the decay takes place, but if coefficient is increasing, then input makes weakened. The  modes in which nanoscale phase diagrams were displaced and went beyond the spinodal  curve in Al-In binary system were found. In this article the phase equilibria in liquid melt of  Al-In binary systems was investigated. The results of the study are the following conclusions:  1. for different concentrations values we calculated dimensional phase diagrams for liquid  melt of Al-In binary system; 2. established that the possibility of disintegration in nanoscale  particle depends on it's size, so for the smaller size, the temperature which allows a particle  to decay is reduced; 3. found that the decay region decreases with increasing heterogeneity of  deposit (Cahn coefficient), that reduces the temperature of the nanoparticles decay; 4. there  is a mode in which the switch qualitative impact of nonlocal interactions influence at decay in  small particles. So when the combination of nonlocal interaction and segregation begin to  contribute to the decay, as opposed to only segregation influence; 5. collapse in nanoscale  particles occurs even in the area of sustainability. So the effect of segregation makes  profitable collapse in nanoparticles than one selection phase with an average concentration.  Cahn coefficient effects on the decay, so if it is small, then the decay takes place, but if  coefficient is increasing, then input makes weakened; 6. for concentrations values that are at  the edges of the spinodal curve, the system must ban for certain values of temperature.  However, to prevent decay the system should increase the temperature, which means that the  phase diagrams for nanosystems will expand and go beyond the macroscopic phase diagram.  We have found the following modes in which nanoscale phase diagrams expanded and moved  out of Al-In phase diagram." @default.
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• W3190641114 date "2014-01-01" @default.
• W3190641114 modified "2023-09-24" @default.
• W3190641114 title "Inflence of non-local chemical interactions on the phase formation in nanosystems" @default.
• W3190641114 hasPublicationYear "2014" @default.
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