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- W3190923537 abstract "The self-nucleation behavior of a polybutene-1/ethylene random copolymer, P(B1-ran-E), which undergoes a complex crystal-crystal transition behavior, has been studied in detail. Similar to PE random copolymers, this material shows a strong melt memory effect even above equilibrium melting point of PB-1 homopolymer. Different polymorphic forms can be obtained when P(B1-ran-E) is cooled from different self-nucleation domains. The trigonal form I′ could only be nucleated in the presence of remaining form I crystals via self-seeding, while the melt memory in Domain IIa could only act as self-nuclei for kinetically favored form II. Furthermore, observations from optical microscopy illustrated that melt memory is able to enhance nucleation density but it does not affect the spherulitic growth rate." @default.
- W3190923537 created "2021-08-16" @default.
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- W3190923537 date "2021-07-31" @default.
- W3190923537 modified "2023-10-16" @default.
- W3190923537 title "Peculiar self‐nucleation behavior of a polybutene‐1/ethylene random copolymer" @default.
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- W3190923537 doi "https://doi.org/10.1002/pcr2.10201" @default.
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