FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3190950994> ?p ?o ?g. }

• W3190950994 endingPage "9571" @default.
• W3190950994 startingPage "9564" @default.
• W3190950994 abstract "The rate of formation of dichloride anions (Cl2•–) in dilute aqueous solutions of HCl (2–100 mmol·kg–1) was measured by the technique of pulse radiolysis over the temperature range of 288–373 K. The obtained Arrhenius dependence shows a concentration averaged activation energy of 7.3 ± 1.8 kJ·mol–1, being half of that expected from the mechanism assuming the •OHCl– intermediate and supporting the ionic equilibrium-based mechanism, i.e., the formation of Cl2•– in the reaction of •OH with a hydronium–chloride (Cl–·H3O+) contact ion pair. Assuming diffusion-controlled encounter of the hydronium and chloride ions and including the effect of the ionic atmosphere, we showed that the reciprocal of τ, the lifetime of (Cl–·H3O+), follows an Arrhenius dependence with an activation energy of 23 ± 4 kJ·mol–1, independent of the acid concentration. This result indicates that the contact pair is stabilized by hydrogen bonding interaction of the solvent molecules. We also found that at a fixed temperature, τ is noticeably increased in less-concentrated solutions (mHCl < 0.01 m). Since this concentration effect is particularly pronounced at near ambient temperatures, the increasing pair lifetime may result from the solvent cage effect enhanced by the presence of large supramolecular structures (patches) formed by continuously connected four-bonded water molecules." @default.
• W3190950994 created "2021-08-16" @default.
• W3190950994 creator A5004984062 @default.
• W3190950994 creator A5020468774 @default.
• W3190950994 creator A5075805169 @default.
• W3190950994 creator A5086875883 @default.
• W3190950994 date "2021-08-12" @default.
• W3190950994 modified "2023-10-18" @default.
• W3190950994 title "Dynamics of Ion Pairing in Dilute Aqueous HCl Solutions by Spectroscopic Measurements of Hydroxyl Radical Conversion into Dichloride Radical Anions" @default.
• W3190950994 cites W1489662751 @default.
• W3190950994 cites W1970122371 @default.
• W3190950994 cites W1995351948 @default.
• W3190950994 cites W1999272564 @default.
• W3190950994 cites W2001911158 @default.
• W3190950994 cites W2003348049 @default.
• W3190950994 cites W2011529186 @default.
• W3190950994 cites W2020318394 @default.
• W3190950994 cites W2021171326 @default.
• W3190950994 cites W2028925907 @default.
• W3190950994 cites W2031246878 @default.
• W3190950994 cites W2032928191 @default.
• W3190950994 cites W2040134513 @default.
• W3190950994 cites W2054549218 @default.
• W3190950994 cites W2057687928 @default.
• W3190950994 cites W2057937496 @default.
• W3190950994 cites W2058955158 @default.
• W3190950994 cites W2067043289 @default.
• W3190950994 cites W2068119928 @default.
• W3190950994 cites W2081997251 @default.
• W3190950994 cites W2085405242 @default.
• W3190950994 cites W2085499449 @default.
• W3190950994 cites W2114919182 @default.
• W3190950994 cites W2130286615 @default.
• W3190950994 cites W2145684457 @default.
• W3190950994 cites W2163719266 @default.
• W3190950994 cites W2280414962 @default.
• W3190950994 cites W2318702332 @default.
• W3190950994 cites W2319127727 @default.
• W3190950994 cites W2319455241 @default.
• W3190950994 cites W2620256418 @default.
• W3190950994 cites W2910040884 @default.
• W3190950994 cites W3001241569 @default.
• W3190950994 cites W3083196081 @default.
• W3190950994 cites W877996488 @default.
• W3190950994 doi "https://doi.org/10.1021/acs.jpcb.1c05642" @default.
• W3190950994 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8404193" @default.
• W3190950994 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34383496" @default.
• W3190950994 hasPublicationYear "2021" @default.
• W3190950994 type Work @default.
• W3190950994 sameAs 3190950994 @default.
• W3190950994 citedByCount "2" @default.
• W3190950994 countsByYear W31909509942022 @default.
• W3190950994 countsByYear W31909509942023 @default.
• W3190950994 crossrefType "journal-article" @default.
• W3190950994 hasAuthorship W3190950994A5004984062 @default.
• W3190950994 hasAuthorship W3190950994A5020468774 @default.
• W3190950994 hasAuthorship W3190950994A5075805169 @default.
• W3190950994 hasAuthorship W3190950994A5086875883 @default.
• W3190950994 hasBestOaLocation W31909509944 @default.
• W3190950994 hasConcept C112887158 @default.
• W3190950994 hasConcept C121332964 @default.
• W3190950994 hasConcept C145148216 @default.
• W3190950994 hasConcept C147789679 @default.
• W3190950994 hasConcept C178790620 @default.
• W3190950994 hasConcept C179104552 @default.
• W3190950994 hasConcept C184651966 @default.
• W3190950994 hasConcept C185592680 @default.
• W3190950994 hasConcept C2182769 @default.
• W3190950994 hasConcept C2777325023 @default.
• W3190950994 hasConcept C2778695967 @default.
• W3190950994 hasConcept C2780471494 @default.
• W3190950994 hasConcept C32909587 @default.
• W3190950994 hasConcept C66887884 @default.
• W3190950994 hasConcept C69357855 @default.
• W3190950994 hasConcept C86183883 @default.
• W3190950994 hasConcept C95121573 @default.
• W3190950994 hasConcept C97355855 @default.
• W3190950994 hasConceptScore W3190950994C112887158 @default.
• W3190950994 hasConceptScore W3190950994C121332964 @default.
• W3190950994 hasConceptScore W3190950994C145148216 @default.
• W3190950994 hasConceptScore W3190950994C147789679 @default.
• W3190950994 hasConceptScore W3190950994C178790620 @default.
• W3190950994 hasConceptScore W3190950994C179104552 @default.
• W3190950994 hasConceptScore W3190950994C184651966 @default.
• W3190950994 hasConceptScore W3190950994C185592680 @default.
• W3190950994 hasConceptScore W3190950994C2182769 @default.
• W3190950994 hasConceptScore W3190950994C2777325023 @default.
• W3190950994 hasConceptScore W3190950994C2778695967 @default.
• W3190950994 hasConceptScore W3190950994C2780471494 @default.
• W3190950994 hasConceptScore W3190950994C32909587 @default.
• W3190950994 hasConceptScore W3190950994C66887884 @default.
• W3190950994 hasConceptScore W3190950994C69357855 @default.
• W3190950994 hasConceptScore W3190950994C86183883 @default.
• W3190950994 hasConceptScore W3190950994C95121573 @default.
• W3190950994 hasConceptScore W3190950994C97355855 @default.
• W3190950994 hasFunder F4320306084 @default.
• W3190950994 hasIssue "33" @default.
• W3190950994 hasLocation W31909509941 @default.

• next