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- W3191379968 abstract "Aqueous zinc ion batteries (ZIBs) have been regarded as one of the most promising candidates for large-scale energy storage systems. Herein, low crystallinity Mn-doped Na5V12O32 (NMVO) with hierarchical rodlike structure has been fabricated by a one-step hydrothermal method. Due to the rational design of the phase and micro/nanostructure, NMVO has numerous voids and defects, which are beneficial to the reversible insertion/extraction of zinc ions. When utilized as cathodes for ZIBs, the electrode delivers a capacity of 256.3 mAh g–1 after 50 cycles at 0.1 A g–1. Moreover, NMVO presents stable cycling performance and rate capability in electrolyte with the addition of Na2SO4. The kinetic characterizations and diffusion mechanism are also studied, and the results demonstrate that the superior zinc ion storage properties of NMVO can be attributed to the equal capacitive contribution, fast ion diffusion coefficient, and favorable structural stability. This strategy can be extended to other electrode materials, such as manganese-based materials and molybdenum-based materials, et al." @default.
- W3191379968 created "2021-08-16" @default.
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- W3191379968 date "2021-08-06" @default.
- W3191379968 modified "2023-09-27" @default.
- W3191379968 title "Rational Design of Hierarchical Mn-Doped Na<sub>5</sub>V<sub>12</sub>O<sub>32</sub> Nanorods with Low Crystallinity as Advanced Cathodes for Aqueous Zinc Ion Batteries" @default.
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- W3191379968 doi "https://doi.org/10.1021/acs.energyfuels.1c02103" @default.
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