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- W3191444220 endingPage "118531" @default.
- W3191444220 startingPage "118531" @default.
- W3191444220 abstract "The incorporation of carbon-based nanomaterials into biopolymer matrix, to provide mechanical reinforcement and to obtain electrically conductive bionanocomposites, requires the homogeneous dispersion of the fillers. Herein, it is investigated the influence of surfactant structures on the dispersibility of multiwalled carbon nanotubes (MWNT) within starch matrix. Three different ionic surfactants, sodium dodecyl sulphate (SDS), cetyltrimethylammonium bromide (CTAB) and sodium cholate (SC), are employed to disperse the MWNT. Films with MWNT-SC show better dispersibility and an increase of about 75% of tensile strength and 60% of Young's modulus compared with films using MWNT-SDS and MWNT-CTAB. Nevertheless, MWNT functionalized with CTAB impart the highest values of antioxidant activity (scavenging activity around 30% in 1.5 h) and electrical conductivity (σ =14.75 S/m) to starch matrix. The properties of starch-based films can be tailored according to the physical adsorption of each surfactant on MWNT surface and/or the interfacial interaction of the surfactant with starch chains. • The best dispersion of MWNT in starch occurs if they are previously dispersed in SC surfactant. • SC surfactant allows getting bionanocomposites with enhanced tensile strength and Young's modulus. • MWNT functionalized with CTAB impart the starch matrix with the highest antioxidant activity. • CTAB allows obtaining the bionanocomposites with electrical conductivity of 14.75 S/m. • The strongest interaction of SC with MWNT and/or with starch compromises the active properties of composites." @default.
- W3191444220 created "2021-08-16" @default.
- W3191444220 creator A5010222652 @default.
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- W3191444220 creator A5039270317 @default.
- W3191444220 creator A5051776486 @default.
- W3191444220 creator A5091180955 @default.
- W3191444220 date "2021-12-01" @default.
- W3191444220 modified "2023-10-11" @default.
- W3191444220 title "Enhancing the dispersibility of multiwalled carbon nanotubes within starch-based films by the use of ionic surfactants" @default.
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- W3191444220 doi "https://doi.org/10.1016/j.carbpol.2021.118531" @default.
- W3191444220 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34560944" @default.
- W3191444220 hasPublicationYear "2021" @default.
- W3191444220 type Work @default.