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• W3191497863 endingPage "150794" @default.
• W3191497863 startingPage "150794" @default.
• W3191497863 abstract "In this paper, CaAl hydrotalcite or hydroxyapatite decorated invasive plant (Solidago canadensis)-derived biochar were synthesized by co-precipitation and high temperature pyrolysis method. The three composites and bare biochar were characterized by Scanning electron microscopy (SEM), X-ray spectroscopy (EDX), the Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometer (XRD), and X-ray photoelectron spectroscopy (XPS) techniques, and employed to remove Eu(III) from wastewater under a series of environmental conditions. The results indicated that the Eu(III) adsorption on [email protected]@HAP was higher than that on BC, [email protected], and [email protected], and belonged to multi-layer adsorption, which was different from the monolayer adsorption of biochar. The adsorption could be fitted best by Langmuir model and the maximum adsorption capacity of Eu(III) on [email protected]@HAP was up to 714 mg/g at pH ~ 6. The characterization results suggested that this excellent adsorption of [email protected]@HAP arose from the abundant P-, C-, O-containing functional groups rather than larger specific surface area. The spectra of XPS, FT-IR, and XRD uncovered that the adsorption mechanisms of Eu(III) on [email protected]@HAP involved surface complexation, ion exchange, and precipitation. Moreover, the absorbed Eu(III) was formed into two precipitate induced by P-containing groups and carbonate groups. This research confirmed [email protected]@HAP is a promising material for the removal of Eu(III) in wastewater." @default.
• W3191497863 created "2021-08-16" @default.
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• W3191497863 date "2021-11-01" @default.
• W3191497863 modified "2023-09-27" @default.
• W3191497863 title "Enhanced adsorption of Eu(III) from wastewater using Solidago canadensis-derived biochar functionalized by Ca/Al-LDH and hydroxyapatite" @default.
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• W3191497863 doi "https://doi.org/10.1016/j.apsusc.2021.150794" @default.
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