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• W3191569082 endingPage "131440" @default.
• W3191569082 startingPage "131440" @default.
• W3191569082 abstract "• NSAIDs construct imprinted pores in UiO-66s for enhancement adsorption of DCF. • NSAIDs imprinted UiO-66s exhibit larger pores and unique surface property. • Adsorbed DCF/Cu(II) act as new bridging sites for UiO-66@NAP to adsorb more DCF/Cu(II). • DCF shows stronger promotion effect of UiO-66@NAP for Cu(II) adsorption in binary system. • UiO-66@NAP shows high adsorbed uptakes for DCF/Cu(II) with 573/135 mg/g in binary system. Competitive adsorption of complex nonsteroidal anti-inflammatory drugs (NSAIDs) from wastewater often reduces the adsorption capacity of object pollutants on most porous materials. To address this issue, NSAIDs molecules were proposed for engineering imprinted pores in UiO-66s to boost their adsorption capacity towards diclofenac sodium (DCF) and Cu(II) in a complex solution. Naproxen (NAP) with proper chemical structure was proved to introduce more imprinted pores (at ~19 Å) with enhanced mesoporous volume, abundant unsaturated metal sites, and terminal hydroxyl groups in UiO-66@NAP. These new intriguing properties awarded high adsorption affinity to UiO-66@NAP for DCF and Cu(II), and their adsorption capacities reached up to 385 and 52 mg/g for single DCF and Cu(II) components, respectively. When DCF and Cu(II) simultaneously appeared in an aqueous solution, DCF was proved to preferentially occupy adsorption sites on UiO-66@NAP with higher adsorption kinetics compared to Cu(II). Afterwards, these pre-adsorbed DCF acted as new adsorption sites to bridge more Cu(II) in the solution. Similarly, the adsorbed Cu(II) on UiO-66@NAP had the same reciprocal bridging effect towards DCF, which realized the synergistic adsorption of DCF and Cu(II) over UiO-66@NAP. Notably, DCF was found to greatly boost the synergistic effect of the Cu(II) adsorption. As a result, UiO-66@NAP exhibited 1.5 and 2.6 times higher uptakes for DCF (573 mg/g) and Cu(II) (135 mg/g) in the binary system compared to their single pollutant system, and its equilibrium adsorption capacity was much higher compared to several state-of-the-art adsorbents. The current work set out a new strategy to modify MOFs for enhanced adsorption of complex NSAID contaminants and revealed a deep understanding of the interactions between NSAIDs and heavy metals ions." @default.
• W3191569082 created "2021-08-16" @default.
• W3191569082 creator A5005744006 @default.
• W3191569082 creator A5006488712 @default.
• W3191569082 creator A5008955331 @default.
• W3191569082 creator A5015887120 @default.
• W3191569082 creator A5036206064 @default.
• W3191569082 creator A5072999973 @default.
• W3191569082 creator A5074403460 @default.
• W3191569082 creator A5085546319 @default.
• W3191569082 date "2021-12-01" @default.
• W3191569082 modified "2023-10-04" @default.
• W3191569082 title "Engineering NSAIDs imprinted UiO-66s for markedly enhanced adsorption of coexisting diclofenac sodium and Cu(II) and their synergistic adsorption mechanism" @default.
• W3191569082 cites W1129409911 @default.
• W3191569082 cites W1971103989 @default.
• W3191569082 cites W1986238480 @default.
• W3191569082 cites W1994640146 @default.
• W3191569082 cites W1999074746 @default.
• W3191569082 cites W2095280288 @default.
• W3191569082 cites W2157206861 @default.
• W3191569082 cites W2168944842 @default.
• W3191569082 cites W2235795390 @default.
• W3191569082 cites W2316304934 @default.
• W3191569082 cites W2465247647 @default.
• W3191569082 cites W2514139663 @default.
• W3191569082 cites W2519879681 @default.
• W3191569082 cites W2536743016 @default.
• W3191569082 cites W2562194812 @default.
• W3191569082 cites W2605905351 @default.
• W3191569082 cites W2750432886 @default.
• W3191569082 cites W2751038132 @default.
• W3191569082 cites W2754546584 @default.
• W3191569082 cites W2754702138 @default.
• W3191569082 cites W2767025169 @default.
• W3191569082 cites W2773791877 @default.
• W3191569082 cites W2781001240 @default.
• W3191569082 cites W2791026221 @default.
• W3191569082 cites W2792976223 @default.
• W3191569082 cites W2797377483 @default.
• W3191569082 cites W2807895252 @default.
• W3191569082 cites W2810316322 @default.
• W3191569082 cites W2884557154 @default.
• W3191569082 cites W2885271591 @default.
• W3191569082 cites W2887238621 @default.
• W3191569082 cites W2889264534 @default.
• W3191569082 cites W2890093811 @default.
• W3191569082 cites W2895391546 @default.
• W3191569082 cites W2898045178 @default.
• W3191569082 cites W2899206852 @default.
• W3191569082 cites W2900346585 @default.
• W3191569082 cites W2901037399 @default.
• W3191569082 cites W2901170167 @default.
• W3191569082 cites W2901701671 @default.
• W3191569082 cites W2902496329 @default.
• W3191569082 cites W2902844124 @default.
• W3191569082 cites W2905221613 @default.
• W3191569082 cites W2908160489 @default.
• W3191569082 cites W2910811559 @default.
• W3191569082 cites W2916459919 @default.
• W3191569082 cites W2923239475 @default.
• W3191569082 cites W2927816227 @default.
• W3191569082 cites W2937517578 @default.
• W3191569082 cites W2938602273 @default.
• W3191569082 cites W2947132733 @default.
• W3191569082 cites W2948044445 @default.
• W3191569082 cites W2954421892 @default.
• W3191569082 cites W2955244058 @default.
• W3191569082 cites W2955385089 @default.
• W3191569082 cites W2964786061 @default.
• W3191569082 cites W2967940189 @default.
• W3191569082 cites W2969573755 @default.
• W3191569082 cites W2970329278 @default.
• W3191569082 cites W2970619231 @default.
• W3191569082 cites W2971414157 @default.
• W3191569082 cites W2972311991 @default.
• W3191569082 cites W2982031047 @default.
• W3191569082 cites W2987727461 @default.
• W3191569082 cites W2991240149 @default.
• W3191569082 cites W2995778077 @default.
• W3191569082 cites W3002968041 @default.
• W3191569082 cites W3004526968 @default.
• W3191569082 cites W3004532372 @default.
• W3191569082 cites W3005099627 @default.
• W3191569082 cites W3006226789 @default.
• W3191569082 cites W3007545035 @default.
• W3191569082 cites W3010838984 @default.
• W3191569082 cites W3011025425 @default.
• W3191569082 cites W3011771236 @default.
• W3191569082 cites W3013438701 @default.
• W3191569082 cites W3014537362 @default.
• W3191569082 cites W3015985366 @default.
• W3191569082 cites W3018063977 @default.
• W3191569082 cites W3023546127 @default.
• W3191569082 cites W3025365420 @default.
• W3191569082 cites W3031615809 @default.
• W3191569082 cites W3033508628 @default.
• W3191569082 cites W3034770675 @default.
• W3191569082 cites W3034933627 @default.

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