FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3191681894> ?p ?o ?g. }

• W3191681894 abstract "Abstract Peat particulate organic matter (POM) has been hypothesized to act as a terminal electron acceptor (TEA) for anaerobic microbial respiration in northern peatlands, thereby lowering dissolved methane (CH 4 ) concentrations in these systems. However, the redox properties of peat POM and an assessment of its redox state in situ remain missing, mainly due to the lack of an accurate analytical approach to quantify the number of electrons that are transferred to/from POM. Here, we first developed a new spectrophotometric method to quantify the number of electrons that are transferable to peat POM—denoted hereafter as electron accepting capacity (EAC)—by reacting POM with the reduced species of the probe compound 4,4’‐bipyridinium‐1,1'bis(2‐ethylsulfonate). Second, we used this analytical approach to quantify the EAC of an oxidized reference POM material (0.38 ± 0.039 mmol e − /g POM) and of redox‐preserved POM from three ombrotrophic bogs in Värmland, Sweden (0.17–0.24 mmol e − /g POM). These EAC values are substantially higher than previous estimates, likely reflecting kinetic artifacts in previous analytical methods. We further established reversible electron transfer to the oxic reference POM over a cycle of electrochemical reduction and O 2 re‐oxidation. Finally, we determined that the EAC of two of the three bog POM samples that were collected anoxically (i.e., redox state‐preserved POM) increased by ∼0.09 mmol e − /g POM upon exposure to air for 8 days, demonstrating that the POM was indeed reduced in situ . Collectively, our results strongly support that POM acts as a sustainable TEA in northern peatlands, which may lower methane release from these systems." @default.
• W3191681894 created "2021-08-16" @default.
• W3191681894 creator A5022337602 @default.
• W3191681894 creator A5037933452 @default.
• W3191681894 creator A5040306582 @default.
• W3191681894 date "2021-08-01" @default.
• W3191681894 modified "2023-10-16" @default.
• W3191681894 title "Redox Properties of Peat Particulate Organic Matter: Quantification of Electron Accepting Capacities and Assessment of Electron Transfer Reversibility" @default.
• W3191681894 cites W1515526034 @default.
• W3191681894 cites W1570621330 @default.
• W3191681894 cites W1577162698 @default.
• W3191681894 cites W1969486586 @default.
• W3191681894 cites W1970218039 @default.
• W3191681894 cites W1974913431 @default.
• W3191681894 cites W1979424160 @default.
• W3191681894 cites W1981851600 @default.
• W3191681894 cites W1983239894 @default.
• W3191681894 cites W1984886207 @default.
• W3191681894 cites W1987205112 @default.
• W3191681894 cites W1990921108 @default.
• W3191681894 cites W1991454477 @default.
• W3191681894 cites W1993733085 @default.
• W3191681894 cites W2007798402 @default.
• W3191681894 cites W2009795600 @default.
• W3191681894 cites W2009983977 @default.
• W3191681894 cites W2011106423 @default.
• W3191681894 cites W2011487077 @default.
• W3191681894 cites W2023575854 @default.
• W3191681894 cites W2023906603 @default.
• W3191681894 cites W2027986195 @default.
• W3191681894 cites W2030082077 @default.
• W3191681894 cites W2032932508 @default.
• W3191681894 cites W2035661238 @default.
• W3191681894 cites W2041252122 @default.
• W3191681894 cites W2041735804 @default.
• W3191681894 cites W2041930594 @default.
• W3191681894 cites W2043378645 @default.
• W3191681894 cites W2050417541 @default.
• W3191681894 cites W2052411439 @default.
• W3191681894 cites W2053255216 @default.
• W3191681894 cites W2054438759 @default.
• W3191681894 cites W2054835895 @default.
• W3191681894 cites W2058839988 @default.
• W3191681894 cites W2059294660 @default.
• W3191681894 cites W2059351450 @default.
• W3191681894 cites W2060577431 @default.
• W3191681894 cites W2068882619 @default.
• W3191681894 cites W2094167057 @default.
• W3191681894 cites W2108273927 @default.
• W3191681894 cites W2108359927 @default.
• W3191681894 cites W2116562890 @default.
• W3191681894 cites W2117624690 @default.
• W3191681894 cites W2130299659 @default.
• W3191681894 cites W2137028777 @default.
• W3191681894 cites W2139680768 @default.
• W3191681894 cites W2141374683 @default.
• W3191681894 cites W2144379882 @default.
• W3191681894 cites W2149533423 @default.
• W3191681894 cites W2151642452 @default.
• W3191681894 cites W2152102479 @default.
• W3191681894 cites W2156073055 @default.
• W3191681894 cites W2156582807 @default.
• W3191681894 cites W2156872309 @default.
• W3191681894 cites W2163721704 @default.
• W3191681894 cites W2166363415 @default.
• W3191681894 cites W2278291610 @default.
• W3191681894 cites W2292560086 @default.
• W3191681894 cites W2313685488 @default.
• W3191681894 cites W2323264858 @default.
• W3191681894 cites W2341382637 @default.
• W3191681894 cites W2600511889 @default.
• W3191681894 cites W2795200791 @default.
• W3191681894 cites W2895094108 @default.
• W3191681894 cites W2901876681 @default.
• W3191681894 cites W2972407136 @default.
• W3191681894 cites W3087913623 @default.
• W3191681894 cites W4235610336 @default.
• W3191681894 doi "https://doi.org/10.1029/2021jg006329" @default.
• W3191681894 hasPublicationYear "2021" @default.
• W3191681894 type Work @default.
• W3191681894 sameAs 3191681894 @default.
• W3191681894 citedByCount "5" @default.
• W3191681894 countsByYear W31916818942022 @default.
• W3191681894 countsByYear W31916818942023 @default.
• W3191681894 crossrefType "journal-article" @default.
• W3191681894 hasAuthorship W3191681894A5022337602 @default.
• W3191681894 hasAuthorship W3191681894A5037933452 @default.
• W3191681894 hasAuthorship W3191681894A5040306582 @default.
• W3191681894 hasBestOaLocation W31916818942 @default.
• W3191681894 hasConcept C107872376 @default.
• W3191681894 hasConcept C122284674 @default.
• W3191681894 hasConcept C123669783 @default.
• W3191681894 hasConcept C178790620 @default.
• W3191681894 hasConcept C179104552 @default.
• W3191681894 hasConcept C185592680 @default.
• W3191681894 hasConcept C18903297 @default.
• W3191681894 hasConcept C24245907 @default.
• W3191681894 hasConcept C2775933976 @default.
• W3191681894 hasConcept C2900893 @default.
• W3191681894 hasConcept C48743137 @default.

• next