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• W3193113418 endingPage "12846" @default.
• W3193113418 startingPage "12836" @default.
• W3193113418 abstract "Transition-metal-catalyzed reductive coupling reactions have emerged as powerful protocols to construct C-C bonds. However, the development of enantioselective C(sp3)-C(sp3) reductive coupling remains challenging. Herein, we report a highly regio-, diastereo-, and enantioselective reductive homocoupling of allylic acetates through cooperative palladium and photoredox catalysis using diisopropylethylamine or Hantzsch ester as a homogeneous organic reductant. This straightforward protocol enables the stereoselective construction of C(sp3)-C(sp3) bonds under mild reaction conditions. A series of C2-symmetrical chiral 1,5-dienes were easily prepared with excellent enantioselectivities (up to >99% ee), diastereoselectivities (up to >95:5 dr), and regioselectivities (up to >95:5 rr). The resultant chiral 1,5-dienes can be directly used as chiral ligands in asymmetric synthesis, and they can be also transformed into other valuable chiral ligands." @default.
• W3193113418 created "2021-08-16" @default.
• W3193113418 creator A5000860216 @default.
• W3193113418 creator A5007936773 @default.
• W3193113418 creator A5011794671 @default.
• W3193113418 creator A5015414692 @default.
• W3193113418 creator A5061910552 @default.
• W3193113418 date "2021-08-05" @default.
• W3193113418 modified "2023-10-15" @default.
• W3193113418 title "Enantioselective Reductive Homocoupling of Allylic Acetates Enabled by Dual Photoredox/Palladium Catalysis: Access to <i>C</i>₂-Symmetrical 1,5-Dienes" @default.
• W3193113418 cites W1504639292 @default.
• W3193113418 cites W1561311795 @default.
• W3193113418 cites W1819780023 @default.
• W3193113418 cites W1893932401 @default.
• W3193113418 cites W1931182516 @default.
• W3193113418 cites W1964297120 @default.
• W3193113418 cites W1964430808 @default.
• W3193113418 cites W1967525658 @default.
• W3193113418 cites W1974660623 @default.
• W3193113418 cites W1977662913 @default.
• W3193113418 cites W1977868435 @default.
• W3193113418 cites W1978004526 @default.
• W3193113418 cites W1978318597 @default.
• W3193113418 cites W1978851116 @default.
• W3193113418 cites W1981997364 @default.
• W3193113418 cites W1983271503 @default.
• W3193113418 cites W1987202299 @default.
• W3193113418 cites W1991192698 @default.
• W3193113418 cites W1992807576 @default.
• W3193113418 cites W1994546592 @default.
• W3193113418 cites W1996941025 @default.
• W3193113418 cites W2001647412 @default.
• W3193113418 cites W2003406192 @default.
• W3193113418 cites W2004017555 @default.
• W3193113418 cites W2007440128 @default.
• W3193113418 cites W2019193983 @default.
• W3193113418 cites W2023224512 @default.
• W3193113418 cites W2029900442 @default.
• W3193113418 cites W2034798181 @default.
• W3193113418 cites W2043760831 @default.
• W3193113418 cites W2050379798 @default.
• W3193113418 cites W2054252013 @default.
• W3193113418 cites W2055446862 @default.
• W3193113418 cites W2060863510 @default.
• W3193113418 cites W2064756573 @default.
• W3193113418 cites W2070751694 @default.
• W3193113418 cites W2071220182 @default.
• W3193113418 cites W2072567793 @default.
• W3193113418 cites W2075667872 @default.
• W3193113418 cites W2077178684 @default.
• W3193113418 cites W2077657121 @default.
• W3193113418 cites W2078742784 @default.
• W3193113418 cites W2082622546 @default.
• W3193113418 cites W2085502493 @default.
• W3193113418 cites W2089659231 @default.
• W3193113418 cites W2093731515 @default.
• W3193113418 cites W2098941592 @default.
• W3193113418 cites W2099531933 @default.
• W3193113418 cites W2101926810 @default.
• W3193113418 cites W2106681560 @default.
• W3193113418 cites W2112485861 @default.
• W3193113418 cites W2115529079 @default.
• W3193113418 cites W2115657493 @default.
• W3193113418 cites W2117123115 @default.
• W3193113418 cites W2119913861 @default.
• W3193113418 cites W2121029205 @default.
• W3193113418 cites W2121360146 @default.
• W3193113418 cites W2130526349 @default.
• W3193113418 cites W2131614569 @default.
• W3193113418 cites W2135481611 @default.
• W3193113418 cites W2137301076 @default.
• W3193113418 cites W2138345440 @default.
• W3193113418 cites W2138891600 @default.
• W3193113418 cites W2140708774 @default.
• W3193113418 cites W2143320596 @default.
• W3193113418 cites W2153680472 @default.
• W3193113418 cites W2288881481 @default.
• W3193113418 cites W2312465499 @default.
• W3193113418 cites W2313885973 @default.
• W3193113418 cites W2316930702 @default.
• W3193113418 cites W2318018747 @default.
• W3193113418 cites W2320091514 @default.
• W3193113418 cites W2326255382 @default.
• W3193113418 cites W2332002457 @default.
• W3193113418 cites W2332979162 @default.
• W3193113418 cites W2342398197 @default.
• W3193113418 cites W2342772717 @default.
• W3193113418 cites W2343933315 @default.
• W3193113418 cites W2413897695 @default.
• W3193113418 cites W2418726947 @default.
• W3193113418 cites W2442602317 @default.
• W3193113418 cites W2466522572 @default.
• W3193113418 cites W2468940798 @default.
• W3193113418 cites W2483185930 @default.
• W3193113418 cites W2498108076 @default.
• W3193113418 cites W2528554534 @default.
• W3193113418 cites W2545762719 @default.
• W3193113418 cites W2559958645 @default.

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