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- W3193131036 endingPage "12045" @default.
- W3193131036 startingPage "12034" @default.
- W3193131036 abstract "The first asymmetric hydrogenation of β,β-diaryl unsaturated phosphonates has been realized for synthesis of β,β-diaryl chiral phosphonates with excellent enantioselectivities (up to 99.9% ee) catalyzed by the Rh-(R,R)-f-spiroPhos complex. Furthermore, this catalyst also exhibits comparably excellent performance for β-aryl-β-alkyl unsaturated phosphonates providing the corresponding chiral phosphonates with up to 99.9% ee values. This methodology provides a straightforward access to asymmetric synthesis of chiral phosphonates." @default.
- W3193131036 created "2021-08-16" @default.
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- W3193131036 date "2021-08-04" @default.
- W3193131036 modified "2023-10-18" @default.
- W3193131036 title "Enantioselective Synthesis of Chiral Phosphonates via Rh/f-spiroPhos Catalyzed Asymmetric Hydrogenation of β,β-Disubstituted Unsaturated Phosphonates" @default.
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- W3193131036 doi "https://doi.org/10.1021/acs.joc.1c01397" @default.
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