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• W3193752108 abstract "Main observation and conclusion The first asymmetric decarboxylative [3+2]‐cycloaddition of ethynyl indoloxazolidones with carboxylic acids has been developed under synergistic catalysis of copper and chiral Lewis base. This protocol provides a direct and modular approach to biologically important pyrrolo[1,2‐ a ]indoles bearing two vicinal stereogenic centers with excellent diastereo‐ and enantioselectivities (up to >20 : 1 dr and >99% ee). In addition, the utility of this methodology was demonstrated by scaled‐up reaction and several synthetic transformations of the cycloadduct." @default.
• W3193752108 created "2021-08-30" @default.
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• W3193752108 date "2021-10-10" @default.
• W3193752108 modified "2023-09-26" @default.
• W3193752108 title "Synergistic Copper and Chiral Lewis Base Catalysis for the Asymmetric Synthesis of Pyrrolo[1,2‐<i>a</i>]indoles" @default.
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• W3193752108 doi "https://doi.org/10.1002/cjoc.202100476" @default.
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