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- W3193834817 abstract "Non-traditional intrinsic luminescence (NTIL) have presented many unique properties, which are quite different from traditional fluorescent materials. In this work, using non-aromatic amines, we found three distinct fluorescent peaks at 400 nm, 440 nm and 500 nm, respectively, in a concentration increasing process. The direct proofs obtained from NMR and other techniques suggested that these peaks might originate from different concentration-dependent aggregates. On the other hand, our results well explained the weird phenomena that NTIL systems presented the excitation-dependent fluorescence (EDF) or excitation-independent fluorescence (EIF) in various cases. We proposed a strategy to prepare fluorescent systems with unique property of tunable emission and controllable EDF or EIF, which would be useful in multi-color imaging applications. • For amine-containing NTIL systems, three concentration-dependent fluorescent peaks were firstly detected, which varied from one to another in a “peak-jump” mode. • Simple aliphatic amines (i.e., TETA) were adopted to prove that the fluorescence might originate from three kinds of concentration-dependent aggregates. • Our results explained the prolonged puzzle that amine-containing NITL systems presented the excitation-dependent/independent fluorescence in different circumstances. • A strategy was proposed to explore applications of multi-color fluorescent imaging based on the unique properties of NTIL." @default.
- W3193834817 created "2021-08-30" @default.
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- W3193834817 date "2021-11-01" @default.
- W3193834817 modified "2023-10-16" @default.
- W3193834817 title "Three distinct concentration-dependent chromophores of non-traditional intrinsic luminescence: The mechanism and special properties" @default.
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- W3193834817 doi "https://doi.org/10.1016/j.jlumin.2021.118401" @default.
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