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- W3194108034 endingPage "230389" @default.
- W3194108034 startingPage "230389" @default.
- W3194108034 abstract "Li7La3Zr2O12 (LLZO) is well received as a solid electrolyte for batteries. Its excellent properties render the implementation of lithium (Li) metal batteries, leading to the improvement of the performances of the batteries. However, a short-circuit failure by Li propagation through the LLZO is a crucial issue and major obstacle for Li-based batteries to overcome. Here, we investigate various growth mechanism of Li penetration through the LLZO. Because of cracks on the surface, the electric field inside the batteries becomes inhomogeneous. Li ions gather near cracks to form lithium dendrites or they also get together along the grain boundaries of LLZO to form the dendrites. Thus, some dendrites grow through grain boundaries once the cracks propagate. If electric field becomes uniform at the interfaces by surface etching or laser treatment, Li dendrite propagation on cracks and/or grain boundaries can be avoided." @default.
- W3194108034 created "2021-08-30" @default.
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- W3194108034 date "2021-10-01" @default.
- W3194108034 modified "2023-10-18" @default.
- W3194108034 title "Short-circuit mechanism induced by crack propagation spurred by inhomogeneous electric field in garnet-based solid electrolyte" @default.
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- W3194108034 doi "https://doi.org/10.1016/j.jpowsour.2021.230389" @default.
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