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- W3194196938 abstract "Abstract Two homoleptic copper(II) complexes [Cu(L1) 2 ] and [Cu(L2) 2 ] with anionic redox‐active ligands were synthesised, one with urea azine (L1) and the other with thio‐urea azine (L2) ligands. One‐electron oxidation of the complexes initiates an unprecedented redox‐induced electron transfer process, leading to monocationic copper(I) complexes [Cu(L1) 2 ] + and [Cu(L2) 2 ] + with two oxidised ligands. While [Cu(L1) 2 ] + is best described as a Cu I complex with two neutral radical ligands that couple antiferromagnetically, [Cu(L2) 2 ] + is a Cu I complex with two clearly different ligand units in the solid state and with a magnetic susceptibility close to a diamagnetic compound. Further one‐electron oxidation of the complex with L1 ligands results in a dication [Cu(L1) 2 ] 2+ , best described as a Cu I complex with a twofold oxidised, monocationic ligand and a neutral radical ligand. The stability in at least three redox states, the accumulation of spin density at the ligands and the facile ligand‐metal electron transfer make these complexes highly attractive for a variety of applications; here the catalytic aerobic oxidation of alcohols to aldehydes is tested." @default.
- W3194196938 created "2021-08-30" @default.
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- W3194196938 creator A5077950297 @default.
- W3194196938 date "2021-09-17" @default.
- W3194196938 modified "2023-10-16" @default.
- W3194196938 title "A Copper(I) Complex with Two Unpaired Electrons, Synthesised by Oxidation of a Copper(II) Complex with Two Redox‐Active Ligands" @default.
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- W3194196938 doi "https://doi.org/10.1002/anie.202109367" @default.
- W3194196938 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8596453" @default.
- W3194196938 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34423532" @default.
- W3194196938 hasPublicationYear "2021" @default.
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