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- W3194315976 abstract "This paper proposes a physio-chemically-based constitutive framework to simulate and predict the response of semi-crystalline low-density polyethylene (LDPE) to severe photo-oxidation. Photo-oxidation induced by exposure to Ultra-Violet (UV) light and oxygen is the dominant degradation mechanism affecting the lifespan of LDPE. In this work, we propose evolution functions for the material properties in the constitutive equations of cite{boyce2000constitutive} to incorporate the effects of photo-oxidation on the mechanical response of LDPE. The evolution functions are based on chemically verified processes that are responsible for material degradation, namely the change in crystallinity and mass loss relative to the initial pristine films over exposure time. Changes in crystallinity and mass loss are characterized by Differential Scanning Calorimetry (DSC) and Quartz Crystal Microbalance with Dissipation Monitoring (QCM-D) experiments, respectively. Connecting the physio-chemical processes affecting polymer network evolution to the mechanical response of LDPE bypasses the need for defining fitting parameters that carry no physical meaning. The developed constitutive framework is validated with respect to a series of in-house uniaxial tensile tests performed on LDPE aged for different UV exposure times. Comparison of the constitutive framework versus experimental mechanical tests also confirms the accuracy of DSC and QCM-D as rigorous techniques to monitor and characterize degradation in LDPE films. The outcome shed light on the evolution of the macromolecular network in LDPE under extreme photo-oxidation and the evolution of the associated mechanical material properties." @default.
- W3194315976 created "2021-08-30" @default.
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- W3194315976 date "2021-08-16" @default.
- W3194315976 modified "2023-09-27" @default.
- W3194315976 title "Physics-based Constitutive Modeling of Photo-oxidative Aging in Semi-Crystalline Polymers based on Chemical Characterization Techniques" @default.
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