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- W3194337454 abstract "Precise synthesis and efficient self-assembly of semiconducting polymers are of great interest. Herein, we report the controlled synthesis of π-conjugated poly(phenyl isocyanide)-b-poly(phenyleneethylene) (PPI-b-PPE) copolymers via chain extension of ethynyl 4-iodobenzene initiated by Pd(II)-terminated helical poly(phenyl isocyanide) (PPI). The in-situ-generated block copolymers self-assembled into various supramolecular architectures depending on the PPE length. The helical PPI segment induced the block copolymers with an appropriate PPE length self-assemble into helical nanofibers with a controlled size and defined helicity. Interestingly, the chiral assemblies of the block copolymers exhibit intense optical activity and emit clear circularly polarized luminescence." @default.
- W3194337454 created "2021-08-30" @default.
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- W3194337454 date "2021-08-23" @default.
- W3194337454 modified "2023-09-24" @default.
- W3194337454 title "Precise Synthesis of π-Conjugated Block Copolymers and Polymerization-Induced Chiral Self-Assembly toward Helical Nanofibers with Circularly Polarized Luminescence" @default.
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- W3194337454 doi "https://doi.org/10.1021/acsabm.1c00763" @default.
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