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- W3194537919 abstract "The electronic structure and properties of Ga 2 O 3 /CuAlO 2 heterojunction have been investigated by computational and experimental methods. The stability and electron transfer effect of Ga 2 O 3 with oxygen-copper terminal of CuAlO 2 are stronger than that of oxygen-aluminum terminal of CuAlO 2 . The Ga 2 O 3 /CuAlO 2 heterojunction has the nested band structure under the most stable condition and it also has the potential advantage of regulating the band structure without doping. The experimental results are in good agreement with the calculated results. • The properties of Ga 2 O 3 /CuAlO 2 heterojunction were investigated. • The stability of Ga 2 O 3 with oxygen-copper terminal of CuAlO 2 are stronger. • Ga 2 O 3 /CuAlO 2 heterojunction has the nested band structure. Because it is difficult to achieve p-type doping of Ga 2 O 3 , Ga 2 O 3 photodetectors based on p-n heterojunction have received widespread attention. As a natural p-type oxide semiconductor, CuAlO 2 is a very potential candidate material for forming a heterojunction with Ga 2 O 3 due to its large hole mobility. In this manuscript, the electronic structure and properties of Ga 2 O 3 /CuAlO 2 heterojunction have been investigated by computational and experimental methods. The binding energy and electron localization functions are calculated to investigate the stability of heterojunction and the bonding mechanism between layers. The electron transfer effect has been explored by calculating the charge density difference, Bader charge and the plane-averaged electrostatic potential drop across the interface. The results show that the stability and electron transfer effect of Ga 2 O 3 with oxygen-copper terminal of CuAlO 2 are stronger than that of oxygen-aluminum terminal of CuAlO 2 . The partial states density indicates that the Ga 2 O 3 /CuAlO 2 heterojunction has the potential advantage of regulating the band structure without doping. Finally, Ga 2 O 3 /CuAlO 2 heterojunction is prepared and the results of XPS and PL test are in good agreement with the calculated results. Our results demonstrate that Ga 2 O 3 /CuAlO 2 heterojunction has a great potential as a candidate structure for the Ga 2 O 3 UV photodetector." @default.
- W3194537919 created "2021-08-30" @default.
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- W3194537919 date "2021-12-01" @default.
- W3194537919 modified "2023-10-04" @default.
- W3194537919 title "Analysis of electronic structure and properties of Ga2O3/CuAlO2 heterojunction" @default.
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- W3194537919 doi "https://doi.org/10.1016/j.apsusc.2021.150826" @default.
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