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• W3195014762 endingPage "14088" @default.
• W3195014762 startingPage "14083" @default.
• W3195014762 abstract "Peyssonnoside A is a marine-derived sulfated diterpenoid glucoside with a unique 5/6/3/6 tetracyclic skeleton with a highly substituted cyclopropane ring deeply embedded into the structure. Herein, we report the first total synthesis of this natural product in a concise, efficient, scalable, and highly diastereoselective fashion. The aglucone peyssonnosol was synthesized in 21% overall yield after 15 steps, featuring a Simmons-Smith cyclopropanation and Mukaiyama hydration, fully controlled by the spatial structure of the substrates." @default.
• W3195014762 created "2021-08-30" @default.
• W3195014762 creator A5014113644 @default.
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• W3195014762 date "2021-08-25" @default.
• W3195014762 modified "2023-09-30" @default.
• W3195014762 title "Concise Total Synthesis of Peyssonnoside A" @default.
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• W3195014762 doi "https://doi.org/10.1021/jacs.1c07135" @default.
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• W3195014762 hasPublicationYear "2021" @default.
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