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- W3195241898 abstract "We have reported iron-based MOFs by sonication of organic linkers with a freshly prepared iron hydroxide, which served as templates to yield iron oxide adsorbents after calcination. The PXRD analysis confirmed the presence of α-Fe2O3 and Na2SO4 in MOF-derived adsorbents. The XPS analysis confirmed the presence of both Fe2+ and Fe3+ species in all MOFs and derived iron oxide adsorbents. These adsorbents were studied for H2S removal in both dry and moist conditions at room temperature. The iron terephthalate MOF-derived iron oxide adsorbent showed the maximum adsorption capacity of 36.2 mg g−1 at moist conditions. The H2S removal process over iron oxide adsorbents was governed by the oxidation of H2S into sulfur and sulfates by Fe3+ and adsorbed oxygen. The spent adsorbent was regenerated by NH4OH to produce ammonium sulfate (liquid fertilizer), which is a novel approach to convert waste into value-added products." @default.
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- W3195241898 date "2021-10-01" @default.
- W3195241898 modified "2023-10-17" @default.
- W3195241898 title "Iron-organic frameworks-derived iron oxide adsorbents for hydrogen sulfide removal at room temperature" @default.
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- W3195241898 doi "https://doi.org/10.1016/j.jece.2021.106195" @default.
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